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2IO(3)^(-)+xI^(-)+12H^(+)rarr6I(2)+6H2O ...

`2IO_(3)^(-)+xI^(-)+12H^(+)rarr6I_(2)+6H_2O`
What is the value of x?

A

`12`

B

`6`

C

`10`

D

`2`

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( x \) in the reaction \[ 2IO_3^{-} + xI^{-} + 12H^{+} \rightarrow 6I_2 + 6H_2O, \] we will determine the change in oxidation states of iodine in the reactants and products. ### Step 1: Determine the oxidation states 1. **Oxidation state of iodine in \( IO_3^{-} \)**: - Let the oxidation state of iodine be \( x \). - The oxidation state of oxygen is \(-2\). - The equation becomes: \[ x + 3(-2) = -1 \implies x - 6 = -1 \implies x = +5. \] - Therefore, the oxidation state of iodine in \( IO_3^{-} \) is \( +5 \). 2. **Oxidation state of iodine in \( I^{-} \)**: - The oxidation state of iodine in \( I^{-} \) is \(-1\). 3. **Oxidation state of iodine in \( I_2 \)**: - The oxidation state of iodine in \( I_2 \) is \( 0 \). ### Step 2: Calculate the change in oxidation states 1. **For \( IO_3^{-} \)**: - Change from \( +5 \) to \( 0 \): \[ \Delta = 5 - 0 = 5. \] - Since there are 2 moles of \( IO_3^{-} \), the total change for \( 2IO_3^{-} \) is: \[ 2 \times 5 = 10. \] 2. **For \( I^{-} \)**: - Change from \( -1 \) to \( 0 \): \[ \Delta = 0 - (-1) = 1. \] - Let \( x \) be the number of moles of \( I^{-} \). The total change for \( xI^{-} \) is: \[ x \times 1 = x. \] ### Step 3: Set up the equation for electron transfer In a balanced redox reaction, the total increase in oxidation states (loss of electrons) must equal the total decrease in oxidation states (gain of electrons). Therefore, we can set up the equation: \[ 10 = x. \] ### Step 4: Solve for \( x \) From the equation above, we find that: \[ x = 10. \] ### Conclusion Thus, the value of \( x \) is \( 10 \). ---
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