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How To Remember Crystal System In A Solid State | Class 12 NCERT | Chemistry | Rupali Ma'am

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In a class, 18 students took Physics, 23 students took Chemistry and 24 students took Mathematics of these 13 took both Chemistry and Mathematics, 12 took both Physics and Chemistry and 11 took both Physics and Mathematics. If 6 students offered all the three subjects, find: (ii) How many took Maths but not Chemistry.

In a class, 18 students took Physics, 23 students took Chemistry and 24 students took Mathematics of these 13 took both Chemistry and Mathematics, 12 took both Physics and Chemistry and 11 took both Physics and Mathematics. If 6 students offered all the three subjects, find: (iii) How many took exactly one of the three subjects.

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Read the passage given below and answer the question: The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since d- electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group. (source: Smeltzer, W. W., & Young, D. J. (1975). Oxidation properties of transition metals. Progress in Solid State Chemistry, 10, 17-54.) In the following question, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the choices on the basis of the above passage. Assertion: CrO crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by chromium ions. Reason: Transition metal oxide may be hexagonal close-packed lattice of oxide ions with metal ions filling the octahedral voids.

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