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Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. N_(2)O_(4) is 66% dissociated into NO_(2) at 340K and 1 atmospheric pressure. The volume occupied by 10gN_(2)O_(4) under these conditions is:

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. For a reversible reaction: 2NO_((g))+O_(2(g))hArr2NO_(2(g)) the rate expression is given as ((dx)/(dt))_("net")=2.6xx10^(3)[NO]^(2)[O_(2)]-4.1[NO_(2)]^(2) . The equilibrium constant of reaction is:

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The following reaction occurs in the Blast Furnace where ions ore is reduced to iron metal : Fe_(2)O_(3)(s)+3CO(g)hArr 2Fe(l)+3CO_(2)(g) Using the Le Chatelier's principle, predict which one of the following will not disturb the equilibrium?