LiAlH_4 / ইথার মিথাইল সায়ানাইডকে | 12 | নাইট্রোজেন ধারণকারী জৈব যৌগ | চে...

0.05 mole of LiAlH_(4) in ether solution was placed in a flask containing 74g (1 mole) of t-butyl alcohol. The product LiAlHC_(12)H_(27)O_(3) weighed 12.6 g. If Li atoms are conserved, the percentage yield is: [Li = 7, Al = 27, H=1, C=12, O=16]

Compound (A) (C_(6)H_(12)O_(2)) on reduction with LiAlH_(4) yielded two compounds (B) and (C ). The compound (B) on oxidation gave (D), which on treatment with aqueous alkail and subsequent heating furnished (E ). The latter on catalytic hydrogenation gave (C ). The compound (D) was oxidised further to give (F) which was found to be a monobasic acid (molecular formula weight = 60.0 ). Deduce the structures of (A), (B), (C ), (D), and (E ).

0.05 mole of LiAlH4 in ether solution was placed in a flask containing 74g (1 mole) of t-butyl alcohol. The product LiAlHC12H27O3 weighed 12.7 g. If Li atoms are conserved, the percentage yield is : (Li = 7, Al = 27, H = 1, C = 12, O = 16).

In the following sequence of reactions a compound A, (molecular formula C_6H_12 O_2 ) with a straight chain structure gives a C_4 carboxylic acid. A is : A underset(H_3O^(+)) overset(LiAlH_4) to B overset("Oxidation") to C_4 - " carboxylic acid"

In the following sequence of reactions a compound A, (molecular formula C_6H_12 O_2 ) with a straight chain structure gives a C_4 carboxylic acid. A is : A underset(H_3O^(+)) overset(LiAlH_4) to B overset("Oxidation") to C_4 - " carboxylic acid"