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Two vessels "A" and "B" are of the same size and are at same temperature.A contains 1g of hydrogen and "B" contains "1g" of oxygen.`P_(A)` and `P_(B` are the pressures of the "],[" gases in "A" and "B" respectively,then `(P_(A))/(P_(B))` is:

A

16

B

8

C

32

D

4

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The correct Answer is:
To solve the problem, we will use the Ideal Gas Law, which states that: \[ PV = nRT \] Where: - \( P \) = pressure of the gas - \( V \) = volume of the gas - \( n \) = number of moles of the gas - \( R \) = universal gas constant - \( T \) = temperature of the gas ### Step 1: Determine the number of moles of each gas 1. **For Hydrogen (H₂)**: - The molar mass of hydrogen (H₂) is approximately 2 g/mol. - Given mass of hydrogen = 1 g. - Number of moles of hydrogen (\( n_A \)): \[ n_A = \frac{\text{mass}}{\text{molar mass}} = \frac{1 \text{ g}}{2 \text{ g/mol}} = 0.5 \text{ moles} \] 2. **For Oxygen (O₂)**: - The molar mass of oxygen (O₂) is approximately 32 g/mol. - Given mass of oxygen = 1 g. - Number of moles of oxygen (\( n_B \)): \[ n_B = \frac{\text{mass}}{\text{molar mass}} = \frac{1 \text{ g}}{32 \text{ g/mol}} = 0.03125 \text{ moles} \] ### Step 2: Apply the Ideal Gas Law to both vessels - For vessel A (Hydrogen): \[ P_A V = n_A RT \implies P_A = \frac{n_A RT}{V} \] - For vessel B (Oxygen): \[ P_B V = n_B RT \implies P_B = \frac{n_B RT}{V} \] ### Step 3: Find the ratio of pressures \( \frac{P_A}{P_B} \) Now we can find the ratio of the pressures: \[ \frac{P_A}{P_B} = \frac{\frac{n_A RT}{V}}{\frac{n_B RT}{V}} = \frac{n_A}{n_B} \] ### Step 4: Substitute the values of \( n_A \) and \( n_B \) Substituting the values we calculated: \[ \frac{P_A}{P_B} = \frac{0.5}{0.03125} = 16 \] ### Conclusion Thus, the ratio of the pressures \( \frac{P_A}{P_B} \) is: \[ \frac{P_A}{P_B} = 16 \] ### Final Answer: \[ \frac{P_A}{P_B} = 16 \] ---
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