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Why does acylation of -NH(2) of aniline ...

Why does acylation of `-NH_(2)` of aniline reduces its activating effect?

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Give reasons : Acetylation of aniline reduces its activation effect.

Acylation of — NH_2 group in aniline reduces its reactivity in electrophilic substitution reactions.

Give reasons for the following (a) Acetylation of aniline reduces its activation effect. (b) CH_(3)NH_(2) is more basic than C_(6)H_(5)NH_(2) . (c) Although -NH_(2) is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

Give reasons for the following (a) Acetylation of aniline reduces its activation effect. (b) CH_(3)NH_(2) is more basiic than C_(6)H_(5)NH_(2) . (c) Although -NH_(2) is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

Give reasons for the following (a) Acetylation of aniline reduces its activation effect. (b) CH_(3)NH_(2) is more basic than C_(6)H_(5)NH_(2) . (c) Although -NH_(2) is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.