Home
Class 11
CHEMISTRY
What fraction (n/N) of the lattice sites...

What fraction (n/N) of the lattice sites are vacant at 298 K for a crystal in which the energy required to make a defect is 1 eV.`(1 eV = 1.602 xx 10^(-19) J)`

Text Solution

Verified by Experts

If `E_upsilon` is the energy required to create one vacant site, then by Boltzmann formula
`n/N=e^(-E_upsilon //kT)` (k=Boltzmann constant =`R/N_0`)
or In `n/N=-E_upsilon / "kT"`
or log `n/N=- E_upsilon / "2.303 kT"=(1.602xx10^(-19))/(2.303(8.314//6.023xx10^23)xx298)`
`=-0.00169185xx10^4 =-16.9185=bar(17).0815`
`n/N`=Antilog `bar(17).0815=1.206xx10^(-17)`
Promotional Banner

Topper's Solved these Questions

  • STATES OF MATTER: SOLID MATTER

    PRADEEP|Exercise PROBLEMS FOR PRACTICE|63 Videos
  • STATES OF MATTER: SOLID MATTER

    PRADEEP|Exercise TEST YOUR GRIP (MULTIPLE CHOICE)|17 Videos
  • STATES OF MATTER: SOLID MATTER

    PRADEEP|Exercise CURIOSITY|3 Videos
  • STATES OF MATTER : GASES AND LIQUIDES

    PRADEEP|Exercise VIII. ASSERTION-REASON TYPE QUESTIONS (TYPE-II)|12 Videos
  • STRUCTURE OF ATOM

    PRADEEP|Exercise Competition Focus (JEE (Main and Advanced)/Medical Entrance (IX. Assertion And Reason Type Questions (Type II))|12 Videos

Similar Questions

Explore conceptually related problems

An electron is accelerated in between two plates maintained at 1000 V . What is the energy in eV acquired by the electrons? (e=1.6 xx10^(-19) C)

Calculate the wavelength and energy of radiation for the elctronic transition form infinity to ground state for one H-atom . Given e_1 =- 13. 6 eV ( 1 1 eV = 1,. 6 xx 10^(-19) J) .

Calculate the velocity of electron ejected from a platium surface when radiation of 200 nm falls on it .The work function of platinum is 5 eV(1 eV = 1.6 xx 10^(-19) J)

The mole fraction of Schottky defect and Frenkel defects, in NaCl crystal at 1000K are respectively. If energy required to produce these defects are 2eV and 3eV respectively. (1eV=1.6xx10^(-19)J and k=1.38xx10^(-23)JK^(-1))

The number of Schottky defects (n) present in an ionic compound containing N ions at temperature T is given by n = Ne^(-E//2KT) , where E is the energy required to create n Schottky defects and K is the Boltzmann constant, If the mole fraction of Schottky defect in NaCl crystal at 2900 K is X , then calculate -ln(x) , Given: DeltaH of Schottky defect = 2 eV and K = 1.38 xx 10^(-23) J K^(-1) 1 eV = 1.608 xx 10^(-19) J

PRADEEP-STATES OF MATTER: SOLID MATTER-ADVANCED PROBLEMS
  1. A bcc lattice is made up of hollow spheres of X. Spheres of solid 'Y' ...

    Text Solution

    |

  2. The density of solid argon is 1.65g//mL at -233^(@)C . If the argon a...

    Text Solution

    |

  3. In the cubic crystal of CsCl (d = 3.97 g cm^(-3)), the eight corners a...

    Text Solution

    |

  4. A compount AB has a rock type structure with A:B=1:1. The formula weig...

    Text Solution

    |

  5. An element crystallises in f.c.c. lattice having edge length 400 p m. ...

    Text Solution

    |

  6. A metallic element crystallizes into a lattice containing sequence of ...

    Text Solution

    |

  7. Calculate the distance between (111) planes in a crystal of calcium....

    Text Solution

    |

  8. Determines the Miller indices of the shaded plane. Coordinates of the ...

    Text Solution

    |

  9. The coordinates of the three corners of a shaded face on a cubic unit ...

    Text Solution

    |

  10. The density of sodium chloride at 25^(@)C "is" 2.163 xx 10 ^(3) " kg...

    Text Solution

    |

  11. What fraction (n/N) of the lattice sites are vacant at 298 K for a cry...

    Text Solution

    |

  12. Metallic magnesium has a hexagonal close packed structure and a densit...

    Text Solution

    |

  13. Calculate the packing fraction and density of diamond if a=3.57 Å. Dia...

    Text Solution

    |

  14. Calculate the packing effeciency of a fcc crystal in which all the te...

    Text Solution

    |

  15. X-ray diffraction studies show that edge length of a unit cell of NaCl...

    Text Solution

    |

  16. A reflaction from (111) planes of a cubic crystal was observed ad at a...

    Text Solution

    |

  17. When an electron in an excited state of Mo atom falls L to K -shell, a...

    Text Solution

    |