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(a) ‘Stability of a crystal is reflected...

(a) ‘Stability of a crystal is reflected in the magnitude of its melting point’. Comment.
(b) The melting points of some compounds are given below : Water = 273 K, Ethyl alcohol = 155.7 K, Diethyl ether = 156.8 K, Methane = 90.5 K. What can you say about the intermolecular forces between these molecules ?

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(a) Higher the melting point, greater are the forces holding the constituent particles together and hence greater is the stability
(b) The intermolecular forces in water and ethyl alcohol are mainly the hydrogen bonding Higher melting point of water than alcohol shows that hydrogen bonding in ethyl alcohol molecules is not a strong as in water molecules. Diethyl ether is a polar molecule. The intermolecular forces present in them are dipole dipole attraction Methane is a non-polar molecule. The only forces present in them are the weak van der Waals forces (London dispersion forces)
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a. "Stability of a crystal is reflected is reflected in the magnitude of its melting points" Comment. b. Melting points of some compounds are given below water = 273 K , ethyl alcohol = 153.7 K , diethyl ether = 156.8 K , methane = 90.5 K . What can you say about the intermolecular forces between the molecules of these compounds?

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A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9 Given: Freezing point depression constant of water (K_(f)^(water)=1.86 K kg mol^(-1)) Freezing point depression constant to ethanol (K_(f)^(ethanol))=2.0 K kg mol^(-1)) Boiling point elevation constant of water (K_(b)^(water))=0.52 K kg mol^(-1)) Boiling point elevation constant of ethanol (K_(b)^(ethanol))=1.2 K kg mol^(-1)) Standard freezing point of water = 273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water = 373 K Standard boiling point of ethanol = 351.5 K Vapour pressure of pure water = 32.8 mm Hg Vapour pressure of pure ethanol = 40 mm Hg Molecular weight of water = 18 g mol^(-1) Molecular weight of ethanol = 46 g mol^(-1) In anwering the following questions consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9 . The boiling point of this solution is

A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9 Given: Freezing point depression constant of water (K_(f)^(water)=1.86 K kg mol^(-1)) Freezing point depression constant to ethanol (K_(f)^(ethanol))=2.0 K kg mol^(-1)) Boiling point elevation constant of water (K_(b)^(water))=0.52 K kg mol^(-1)) Boiling point elevation constant of ethanol (K_(b)^(ethanol))=1.2 K kg mol^(-1)) Standard freezing point of water = 273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water = 373 K Standard boiling point of ethanol = 351.5 K Vapour pressure of pure water = 32.8 mm Hg Vapour pressure of pure ethanol = 40 mm Hg Molecular weight of water = 18 g mol^(-1) Molecular weight of ethanol = 46 g mol^(-1) In anwering the following questions consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. The freezing point of the solution M is

A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9 Given: Freezing point depression constant of water (K_(f)^(water)=1.86 K kg mol^(-1)) Freezing point depression constant to ethanol (K_(f)^(ethanol))=2.0 K kg mol^(-1)) Boiling point elevation constant of water (K_(b)^(water))=0.52 K kg mol^(-1)) Boiling point elevation constant of ethanol (K_(b)^(ethanol))=1.2 K kg mol^(-1)) Standard freezing point of water = 273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water = 373 K Standard boiling point of ethanol = 351.5 K Vapour pressure of pure water = 32.8 mm Hg Vapour pressure of pure ethanol = 40 mm Hg Molecular weight of water = 18 g mol^(-1) Molecular weight of ethanol = 46 g mol^(-1) In anwering the following questions consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. The vapour pressure of the solution M is

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