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Predict the sign of entropy change in ea...

Predict the sign of entropy change in each of the following `:`
(i) `H_(2) ( ` at 298 K, 1 atm ) `rarr H_(2)` at 298 K, 10 atm)
(ii) `H_(2)O( ` at 298K, 1 atm ) ` rarr H_(2)O` ( at 330K, 1atm)
(iii) `2NH_(4)NO_(3)(s) rarr 2N_(2)(g)+4H_(2)O(g) +O_(2)(g)`
(iv) Crystallization of copper sulphate from its saturated solution.
(v) `2SO_(2)(g) +O_(2)(g) hArr 2SO_(3)(g)`

Text Solution

AI Generated Solution

To predict the sign of entropy change (ΔS) for each of the given scenarios, we will analyze the changes in the system based on the principles of thermodynamics. ### Solution Steps: **(i) H₂ (at 298 K, 1 atm) → H₂ (at 298 K, 10 atm)** - When the pressure of a gas increases, the molecules are forced closer together, leading to a decrease in randomness or disorder. - Therefore, the sign of entropy change (ΔS) is **negative**. ...
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