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The standard free energy change for a re...

The standard free energy change for a reaction is -212.3 kJ `mol^(-1)`. If the enthalpy change of the reaction is `-216 kJ mol^(-1)` , calculate the entropy change for the reaction.

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To calculate the entropy change (ΔS) for the reaction, we will use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] Where: - ΔG = standard free energy change - ΔH = enthalpy change - T = temperature in Kelvin - ΔS = entropy change ### Step 1: Identify the given values From the problem, we have: - ΔG = -212.3 kJ/mol - ΔH = -216 kJ/mol - Temperature (T) = 298 K (since it is not mentioned, we assume room temperature) ### Step 2: Rearrange the Gibbs free energy equation to solve for ΔS We can rearrange the equation to isolate ΔS: \[ \Delta S = \frac{\Delta H - \Delta G}{T} \] ### Step 3: Substitute the known values into the equation Now, substitute the values we have into the equation: \[ \Delta S = \frac{-216 \text{ kJ/mol} - (-212.3 \text{ kJ/mol})}{298 \text{ K}} \] ### Step 4: Simplify the equation Calculating the numerator: \[ -216 + 212.3 = -3.7 \text{ kJ/mol} \] Now substituting this back into the equation for ΔS: \[ \Delta S = \frac{-3.7 \text{ kJ/mol}}{298 \text{ K}} \] ### Step 5: Perform the division Now, calculate ΔS: \[ \Delta S = -0.0124 \text{ kJ/mol/K} \] ### Step 6: Convert ΔS to J/mol/K Since entropy is often expressed in J/mol/K, we convert kJ to J by multiplying by 1000: \[ \Delta S = -12.4 \text{ J/mol/K} \] ### Final Answer The entropy change (ΔS) for the reaction is: \[ \Delta S = -12.4 \text{ J/mol/K} \] ---
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