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In an irreversible process taking place at constant `T` and `P` and in which only pressure-volume work is being done, the change in Gibbs free energy `(dG)` and the change in entropy `(dS)` satisfy the criteria

A

`( dS) _(V,E) gt 0 , (dG) _(T,P) lt 0`

B

`( dS) _(V,E) = 0 , (dG) _(T,P) = 0`

C

`( dS) _(V,E) = 0 , (dG) _(T,P) gt 0`

D

`( dS) _(V,E) lt 0 , (dG) _(T,P) lt 0`

Text Solution

Verified by Experts

The correct Answer is:
a
For irrev., i.e.,spontaneous process , `d S gt 0, dG lt0`.
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