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If K lt1.0, what will be the value of De...

If `K lt1.0`, what will be the value of `DeltaG^(@)` out of the following `?`

A

`1.0`

B

Zero

C

Negative

D

Positive

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The correct Answer is:
To determine the value of \(\Delta G^\circ\) when the equilibrium constant \(K < 1\), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Relationship**: The relationship between the standard Gibbs free energy change (\(\Delta G^\circ\)) and the equilibrium constant (\(K\)) is given by the equation: \[ \Delta G^\circ = -RT \ln K \] where \(R\) is the universal gas constant and \(T\) is the temperature in Kelvin. 2. **Analyze the Condition \(K < 1\)**: Since \(K < 1\), it implies that the natural logarithm of \(K\) will be negative because the logarithm of a number less than 1 is always negative: \[ \ln K < 0 \] 3. **Substitute into the Equation**: Substituting the negative value of \(\ln K\) into the equation for \(\Delta G^\circ\): \[ \Delta G^\circ = -RT \ln K \] Since \(\ln K < 0\), we have: \[ \Delta G^\circ = -RT (\text{negative value}) = \text{positive value} \] 4. **Conclusion**: Therefore, if \(K < 1\), \(\Delta G^\circ\) will be greater than 0, indicating that the reaction is non-spontaneous under standard conditions. ### Final Answer: \(\Delta G^\circ > 0\) ---

To determine the value of \(\Delta G^\circ\) when the equilibrium constant \(K < 1\), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Relationship**: The relationship between the standard Gibbs free energy change (\(\Delta G^\circ\)) and the equilibrium constant (\(K\)) is given by the equation: \[ \Delta G^\circ = -RT \ln K ...
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PRADEEP-THERMODYNAMICS-TEST YOUR GRIP( MULTIPLE CHOICE QUESTIONS)
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  2. Which of the following are not state functions? (I) q+w (II)q (I...

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  4. Which of the following reactions is defines Delta(f)H^(Theta)?

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  5. The lattice enthalpy and hydration enthalpy of four compounds are give...

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  7. The species which by definition has zero standard molar enthalpy of fo...

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  8. Thermodynamically the most stable form of carbon is

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  9. The sublimation energy of I(2) (solid) is 57.3 KJ/mole and enthalpy o...

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  10. Given that C + O(2) rightarrow CO(2), Delta H^(@) = - x k J 2CO +O...

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  11. The bond energies of H--H , Br--Br and H--Br are 433,, 192 and 364KJmo...

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  12. Predict the sign of DeltaS^(@) for the following reaction : 2H(2)S (...

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  13. Which one of the following demonstrates a decrease in entropy ?

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  14. If the enthalpy change for the transition of liquid water to steam is ...

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  15. A catalyst

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  16. A process is taking place at constant temperature and pressure. Then

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  17. In an irreversible process taking place at constant T and P and in whi...

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  18. A reaction occurs spontaneously if

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  19. Ths standard free energy change Delta G^(@) is related to K (equilibri...

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  20. If K lt1.0, what will be the value of DeltaG^(@) out of the following ...

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