Home
Class 11
CHEMISTRY
Calculate the entropy change in surround...

Calculate the entropy change in surroundings when `1.00` mol of `H_(2)O(l)` is formed under standard conditions, `Delta_(r )H^(Θ) = -286 kJ mol^(-1)`.

Text Solution

Verified by Experts

`H_(2)(g)+(1)/(2)O_(2)(g)rarrH_(2)O(l), Delta_(f)H^(@) = - 286kJ mol^(-1)`
This means that when 1 mol of `H_(2)O(l)`, is formed , 286kJof heat is released . This heat is absorbed by the surroundings, i.e., `q_(surr)= +286 kJ mol^(-1)`
`:. DeltaS = ( q_(surr))/(T) = ( 286kJ mol^(-1))/( 298K) = 0.9597kJ K^(-1) mol^(-1)= 959.7 JK^(-1) mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    PRADEEP|Exercise NCERT SUPPLEMENTARY EXERCISE|6 Videos
  • THERMODYNAMICS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS( MULTIPLE CHOICE QUESTIONS-I)|14 Videos
  • THERMODYNAMICS

    PRADEEP|Exercise CONCEPTUAL QUESTIONS( III.Enthalpy change and its relation with internal energy change)|13 Videos
  • STRUCTURE OF ATOM

    PRADEEP|Exercise Competition Focus (JEE (Main and Advanced)/Medical Entrance (IX. Assertion And Reason Type Questions (Type II))|12 Videos

Similar Questions

Explore conceptually related problems

Calculate the entropy change for vaporization of 1mol of liquid water to stem at 100^(@)C , if Delta_(V)H = 40.8 kJ mol^(-1) .

Calculate the entropy change of n-hexane when 1 mole of it evaporates at 341.7 K (Delta_(vap) H = 29.0 kJ "mol"^(-1)) .

Calculate the entropy change of n -hexae when 1mol of it evaporates at 341.7K (Delta_(vap)H^(Theta) = 290.0 kJ mol^(-1))

The dissolution of 1 mol e of NaOH_((s)) in 100 mol e of H_(2)O_((l)) give rise to evolution of heat equal to -42.34kJ . However if 1 mol e of NaOH_((s)) is dissolved in 1000 mol e of H_(2)O_((l)) , the heat given out is 42.76kJ . What would be enthalpy change when 900 mole of H_(2)O_((l)) are added to a solution containing 1 mole of NaOH_((s)) in 100 mole of H_(2)O ?

PRADEEP-THERMODYNAMICS-NCERT QUESTIONS AND EXERCISES WITH ANSWERS
  1. The enthalpies of all elements in their standard states are :

    Text Solution

    |

  2. DeltaU^(@) of combustion of methane is -X kJmol^(-1). The value of Del...

    Text Solution

    |

  3. The enthalpy of combustion of methane, graphite and dihydrogen at 298 ...

    Text Solution

    |

  4. A reaction, A+B rarrC + D+ q is found to havea positive entropy change...

    Text Solution

    |

  5. In a process, 701 J of heat is absorbed by a system and 394 J of work ...

    Text Solution

    |

  6. The reaction of cyanamide, NH(2)CN(s), with dioxygen was carried out i...

    Text Solution

    |

  7. Calculate the number of KJ necessary to raise the temperature of 60.0 ...

    Text Solution

    |

  8. Calcualte the enthalpy change on freezing of 1.0 mole of water at 10.0...

    Text Solution

    |

  9. Enthalpy of combustion of carbon to CO(2) is -393.5 kJ mol^(-1). Calcu...

    Text Solution

    |

  10. Enthalpies of formation of CO(g), CO(2)(g),N(2)O(g) and N(2)O(4)(g) ar...

    Text Solution

    |

  11. Given N(2)(g)+3H(2)(g)rarr2NH(3)(g),Delta(r)H^(Ө)= -92.4 kJ mol^(-1...

    Text Solution

    |

  12. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

    Text Solution

    |

  13. Calculate the enthalpy change for the process C Cl(4)(g) rarr C(g)+4...

    Text Solution

    |

  14. For an isolated system, DeltaU = 0 , what will be DeltaS?

    Text Solution

    |

  15. For the reaction at 298 K 2A+B rarr C DeltaH=400 kJ mol^(-1) and D...

    Text Solution

    |

  16. For the reaction 2Cl(g) rarr Cl(2)(g), what are the signs of DeltaH ...

    Text Solution

    |

  17. For the reaction, 2A(g)+B(g) rarr 2D(g) DeltaU^(Θ)=-10.5 kJ and De...

    Text Solution

    |

  18. The equilibrium constant for a reaction is 10. What will be the value ...

    Text Solution

    |

  19. Comment on the thermodynamic stability of NO(g), given 1/2N(2)(g)+1/...

    Text Solution

    |

  20. Calculate the entropy change in surroundings when 1.00 mol of H(2)O(l)...

    Text Solution

    |