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Write a general expression for the entro...

Write a general expression for the entropy change during a phase transformation, or Give a relation between entropy change and heat absorbed or evolved for a reversible reaction occuring at temperature T.

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To derive the general expression for the entropy change during a phase transformation, we can follow these steps: ### Step-by-Step Solution: 1. **Understand Phase Transformation**: - A phase transformation occurs when a substance changes from one state of matter to another, such as solid to liquid (melting), liquid to gas (vaporization), or solid to gas (sublimation). 2. **Identify the Conditions**: ...
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Work done by the system in isothermal reversible process is w_(rev.)= -2.303 nRT "log"(V_(2))/(V_(1)) . Also in case of adiabatic reversible process work done by the system is given by: w_(rev.) = (nR)/(gamma -1) [T_2 - T_1] . During expansion disorder increases and the increase in disorder is expressed in terms of change in entropy DeltaS = q_(rev.)/T . The entropy changes also occurs during transformation of one state to other end expressed as DeltaS = DeltaH/T . Both entropy and enthalpy changes obtained for a process were taken as a measure of spontaniety of process but finally it was recommended that decrease in free energy is responsible for spontaniety and DeltaG=DeltaH - T DeltaS . The heat of vaporisation and heat of fusion of H_2O are 540 cal//g and 80 cal//g . This ratio of (DeltaS_(vap.))/(DeltaS_("fusion")) for water is:

PRADEEP-THERMODYNAMICS-ADDITIONAL QUESTIONS(VERY SHORT ANSWER QUESTIONS)
  1. Comment on the bond energies of four C-H bonds present in CH(4).

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  2. What is the limitation of the first law of thermodynamics?

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  3. Write a general expression for the entropy change during a phase trans...

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  4. What is entropy? Give its units.

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  5. Predict the sign of entropy change in the following reaction : (i) O...

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  6. What is the effect of temperature on entropy?

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  7. Entropy of diamond is less than that of graphite.What conclusion do y...

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  8. Explain the terms entropy and free energy.Why does entropy of a solid ...

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  9. What do you meanby Entropy of vaporisation or Entropy of fusion or E...

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  10. Give a statement which includes the main ideas of the first law and se...

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  11. State the second law of thermodynamics.

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  12. What is the Gibbs Helmhotz equation ?

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  13. What is free energy? How is it related to the spontaneity of a reactio...

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  14. How are internal energy change( at constant pressure) , free energy ch...

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  15. How are the following related ? ( Give mathematical relation ) (i) F...

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  16. A reversible reaction has DeltaG^(@) negative for forward reaction ? ...

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  17. What is the criteria for spontaneity in terms of free energy change ...

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  18. Why for predicting the spontaneity of a reaction , free energy criteri...

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  19. State the thermodynamic condition of spontaneous occurance of a proces...

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  20. Why a non- spontaneous reaction becomes spontaneous when coupled with ...

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