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q and w are not state function but q + w...

q and w are not state function but q + w is state function. Why?

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A: q and w are path function R: q + w is a state function

Heat and work are not state function but their sum is a state function.

Neither q nor w is a state function but q +w is a state function. Explain why?

The first law of thermodynamics was given as q=DeltaU+(-w) , where q is heat given to a system and DeltaU represents increase in internal energy and -w is work done by the system. Various processes such as isothermal, adiabatic, cyclic, isobaric and isochoric process in terms of I law of thermodynamics leads for important results. The molar heat capacity for 1 mole of monoatomic gas is 3/2 R at constant volume and 5/2 R at constant pressure. Which of the following statements are correct? (1) Both work and heat appears at the boundaries of system. (2) Heat given to a system is given +ve sign. (3) Heat given to a system is equal to increase in internal energy under isothermal conditions (4) Heat given to a system is used to increase internal energy under isochoric conditions (5) Both work and heat are not state functions but their sum (q+w) is state function.

A state function is that -

Assertion: Work and internal energy are not state functions. Reason: The sum of q+w is a state function.

Assertion :- q+w is a state function. Reason :- sum of two path function is state function.

PRADEEP-THERMODYNAMICS-SHORT ANSWER QUESTIONS
  1. How will you distinguish between the two? (i) Open and closed system...

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  2. State the law of conservation of energy. Give some examples in which t...

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  3. q and w are not state function but q + w is state function. Why?

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  4. Discuss the significance of the mathematical expression in which the h...

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  5. State first law of thermodynamics.Write it mathematical expression.

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  6. Briefly explain the term 'enthalpy' . How does if differ from internal...

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  7. Starting with the thermodynamic relationships, DeltaU=q-P DeltaV and H...

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  8. Starting with the thermodynamic relationshipsH = U+PV derive the foll...

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  9. Derive the relationship between heat of reaction at constant pressureq...

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  10. What do you understand by K(c) and K(p) ? Derive a relationship betwee...

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  11. Explain the calculations involved in the determination of heat of comb...

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  12. Define DeltaH.What will be the sign of DeltaH in (i) exothermic reac...

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  13. Briefly explain the term 'standard heat of formation' . What is standa...

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  14. What is the basic difference between enthalpy of formation and enthalp...

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  15. Define Hess's law of constant heat summation.

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  16. Define the term 'bond enthalpy'.Why an average value is taken in the p...

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  17. What is meant by average bond energy? In what way is it different from...

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  18. Explain spontaneous and non-spontaneous processes.

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  19. What is meant by enthalpy ? Can a decrease in enthalpy be the criterio...

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  20. Neither the enthalpy change nor the entropy change alone can be used t...

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