When you freeze water in your freezer to make ice cubes,the amount of order in the molecules ofwater increases. However , second law of thermodynamics says that the amount of order in the isolated system can only stay constant or decrease with time. How can thus making of ice violate second law ?

Options

A. because water expands during ice formation
B. because ice formation takes place at `0^(@)C`
C. because ice issolid
D. because ice cubes do not constitute isolated system.

Explanation

To understand how the freezing of water into ice cubes does not violate the second law of thermodynamics, we need to analyze the concepts of order, entropy, and isolated systems step by step.

### Step-by-Step Solution:

1. **Understanding Freezing Process**:
- When water freezes, it transitions from a liquid state to a solid state (ice). In this process, the molecules of water become more ordered as they arrange themselves into a crystalline structure.

2. **Change in Entropy**:
- Entropy is a measure of disorder or randomness in a system. In the case of freezing, the entropy of the water decreases because the water molecules have less freedom to move in the solid state compared to the liquid state.

3. **Second Law of Thermodynamics**:
- The second law states that in an isolated system, the total entropy can never decrease over time. It can only stay constant or increase. This means that the overall disorder of an isolated system should not decrease.

4. **Isolated vs. Non-Isolated Systems**:
- The key point here is that the freezing of water does not occur in an isolated system. The freezer is not isolated; it exchanges heat with its surroundings. When water freezes, it releases heat to the environment, which increases the entropy of the surroundings.

5. **Entropy Change in the Surroundings**:
- While the entropy of the water decreases as it freezes, the entropy of the surroundings increases due to the heat released. The total change in entropy (system + surroundings) must be considered.

6. **Conclusion**:
- Therefore, even though the entropy of the water decreases when it freezes, the overall entropy of the universe (system + surroundings) increases. This is consistent with the second law of thermodynamics, which applies to isolated systems.

### Final Answer:
The making of ice does not violate the second law of thermodynamics because the system (ice) is not isolated. The heat released during the freezing process increases the entropy of the surroundings, leading to an overall increase in entropy.