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Write resonating structures for CH2 = CH...

Write resonating structures for `CH_2 = CHCHO`. Indicate relative stability of the contributing structures :

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Structure (I) is most stable since both C and O atom has an octet of electrons and none of these atoms carries any charge. Structures (II and III) both involve separation of charge and hence both are less stable than structure (I). However, structure (II) is more stable than structure (III) since it carries a -ve charge on the more electronegative O atom and +ve charge on the less electronegative (C) atom while is structure (III), the more electronegative O atom carries the +ve charge while the less electronegative C atom carries the -ve charge. Thus, the decreasing order of stability is : `I gt II gt III`
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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Competition Focus (Jee (Main and Advanced)/Medical Entrance) VIII. Assertion-Reason Type Questions
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  2. Statement-1 . The IUPAC name of the compound {:(CH(2)=CH-CH=CH-CH-C-...

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  3. Assertion: CH(3)CHO and CH(2)=CHOH are resonance structures. Reason:...

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  4. Statement-1. Simple carbanions are usually pyramidal but allyl carbani...

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  5. Assertion: tert-Butyl carbanion is less stable than methyl carbanion. ...

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  6. Assertion: Free redicals are always planer. Reason: They can achieve...

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  7. Assertion: Nitrenes cannot be isolated. Reason: Nitrene are the nitr...

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  8. Statement-1. Beilstein test can be used to detect fluorine in the orga...

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  9. Statement-1. Lassaigne's extract is boiled with dil. HNO(3) before tes...

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  10. Assertion : Butane and 2-methyl butane are chain isomers. Reason : B...

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  11. Assertion :But-1-ene2-Methylprop-1-ene are position isomers. Reason Po...

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  12. Assertion : All the carbon atoms of but-2-ene lie in one plane. Reas...

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  13. Assertion : In CH(2)=C=CH(2), all the carbon atoms are sp^(2)-hybridiz...

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  14. Assertion : A free radical is paramagnetic species. Reason : A free ...

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  15. (A) Tertiary carbocations are generally formed more easily than primar...

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  16. Assertion: Alkyl carbonaions like ammonia have pyramidal shape. Reas...

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  17. (A) Tertiary butyl carbonion is less stable than methyl carbanion. (...

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  18. (A) Allyl free radical is more stable than simple alkyl free radical. ...

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  19. Assertion (A) o-and p-nitrophenol can be separated by steam distillati...

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  20. Assertion : Essential oils are purified by steam distillation. Reaso...

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  21. (A) Oils are purified by steam distillation. (R) The compounds which...

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