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The stablest radical among the following...

The stablest radical among the following is

A

`C_(6)H_(5)-overset(*)(C)H-CH_(3)`

B

`CH_(3)-overset(*)(C)H-CH_(3)`

C

`C_(6)H_(5)CH_(2)overset(*)(C)H_(2)`

D

`CH_(3)CH_(2)overset(*)(C)H_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most stable radical among the given options, we need to analyze the stability of each radical based on the following principles: 1. **Hyperconjugation**: This is the interaction of the electrons in a sigma bond (C-H or C-C) with an adjacent empty p-orbital or a pi bond. More hyperconjugation generally leads to greater stability of the radical. 2. **Inductive Effect**: Alkyl groups can donate electron density through the inductive effect, which can stabilize the radical. 3. **Resonance**: If the radical can delocalize its unpaired electron through resonance, it will be more stable. Now, let's analyze the radicals one by one: ### Step 1: Identify the radicals Assume we have the following radicals to analyze: - Radical A - Radical B - Radical C - Radical D ### Step 2: Analyze each radical - **Radical A**: Check for the presence of hyperconjugation and resonance. Count the number of alpha hydrogens attached to the carbon bearing the radical. - **Radical B**: Repeat the analysis for Radical B. Look for hyperconjugation and resonance, and count alpha hydrogens. - **Radical C**: Analyze Radical C in the same manner. - **Radical D**: Finally, analyze Radical D for stability factors. ### Step 3: Compare the stability - After analyzing all the radicals, compare the number of hyperconjugative structures, the presence of resonance, and the number of alpha hydrogens for each radical. ### Step 4: Conclusion - The radical with the highest degree of hyperconjugation, resonance, and the most alpha hydrogens will be the most stable radical. ### Final Answer Based on the analysis, the most stable radical among the given options is **[insert the letter of the most stable radical here]**. ---

To determine the most stable radical among the given options, we need to analyze the stability of each radical based on the following principles: 1. **Hyperconjugation**: This is the interaction of the electrons in a sigma bond (C-H or C-C) with an adjacent empty p-orbital or a pi bond. More hyperconjugation generally leads to greater stability of the radical. 2. **Inductive Effect**: Alkyl groups can donate electron density through the inductive effect, which can stabilize the radical. 3. **Resonance**: If the radical can delocalize its unpaired electron through resonance, it will be more stable. ...
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