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Classify the following reactions in one ...

Classify the following reactions in one of the reaction type studied in this unit.
(a) `CH_(3)CH_(2)Br+HS^(-)toCH_(3)CH_(2)SH+Br^(-)`
(b) `(CH_(3))_(2)C=CH_(2)+HCl to(CH_(3))_(2)ClC-CH_(3)`
(c) `CH_(3)CH_(2)Br+HO^(-)toCH_(2)=CH_(2)+H_(2)O+ Br^(-)`
(d) `(CH_(3))_(3)C-CH_(2)OH+HBrto(CH_(3))_(2)CBrCH_(2)CH_(2)CH_(3)+H_(2)O`

Text Solution

Verified by Experts

(a) Nucleophilic substitution
(b) Electrophilic addition
(c) Bimolecular elimination
(d) Nucleophilic subtitution with rearrangement.
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Classify the following in one of the reaction type studied. (a) CH_3CH_2Br + HS^(Ө) rarr CH_3CH_2SH + Br^(Ө) (b) (CH_3)_2C = CH_2 + HC1 rarr (CH_3)_2 C1C - CH_3 ( c) (CH_3)_3 C - CH_2OH + HBr rarr (CH_3)_2 CBr CH_2 CH_3 (d) CH_3CH_2 Br + HO^(Ө) rarr CH_2 = CH_2 .

Predict the order of reactivity of the following compounds in dehydrohalogenation: (a) CH_(3)CH_(2)CH_(2)CH_(2)Cl, (CH_(3))_(2)CHCH_(2)Cl, (CH_(3))_(2)CH-CH_(2)Br, CH_(3)CH(Br)CH_(2)CH_(3), (CH_(3))_(3)C-Br (b) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)CH_(2)Br, (CH_(3))_(2)CHCH_(2)Br, (CH_(3))_(3)C CH_(2)Br

Write IUPAC names of the following compounds : (a) CH_(3)CH(Cl)CH(Br)CH_(3) (b) CHF_(2)CBrClF (c) ClCH_(2)C-=C CH_(2)Br (d) (C Cl_(3))_(3)C Cl (e) CH_(3)C(p-ClC_(6)H_(4))_(2)CH(Br)CH_(3) (f) (CH_(3))_(3)C CH=C(Cl)C_(6)H_(4)I-p (g) CH_(3)CHCl(CH_(2))_(2)C Cl_(2)C_(2)H_(5)

Arrange the following compounds in the increasing order of their boiling points: CH_(3)CH_(2)CH_(2)CHO, CH_(3)CH_(2)CH_(2)CH_(2)OH, H_(5)C_(2)-O-C_(2)H_(5),CH_(3)CH_(2)CH_(2)CH_(3)

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