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Nitromethane exists in the aci-form but ...

Nitromethane exists in the aci-form but nitrobenzene does not. Explain why ?

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To understand why nitromethane exists in the aci-form while nitrobenzene does not, we need to analyze the structures and stability of both compounds. ### Step 1: Understanding the Structures - **Nitromethane (CH3NO2)**: It has a nitro group (-NO2) attached to a methyl group (-CH3). The aci-form of nitromethane is represented as CH2(OH)NO2, where the nitrogen is bonded to an -OH group instead of a hydrogen atom. - **Nitrobenzene (C6H5NO2)**: It has a nitro group attached to a benzene ring. The aci-form of nitrobenzene would involve a similar transformation, but the stability of this form is different. ### Step 2: Stability of Aci-Form vs Nitro-Form - **Aci-Form of Nitromethane**: In nitromethane, the aci-form is more stable due to the resonance stabilization provided by the nitro group. The resonance structures allow for delocalization of electrons, which stabilizes the aci-form. ...
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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Additional Questions (Very short Answer Questions)
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