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CH(2)=CH^(-) is a better nucleophile tha...

`CH_(2)=CH^(-)` is a better nucleophile than `HC -= C^(-)`. Explain.

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To understand why \( CH_2=CH^- \) is a better nucleophile than \( HC \equiv C^- \), we need to analyze the acidity of the corresponding acids and the basicity of the conjugate bases. ### Step 1: Identify the acids The conjugate acids of the nucleophiles are: - For \( CH_2=CH^- \), the conjugate acid is \( CH_2=CH_2 \) (ethene). - For \( HC \equiv C^- \), the conjugate acid is \( HC \equiv CH \) (ethyne). ### Step 2: Compare the acidity of the conjugate acids ...
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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Additional Questions (Very short Answer Questions)
  1. Select electrophiles out of the following : H^(+), Na^(+), Cl^(-), C...

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  2. H(2)C = O or CH(3)CN acts as a nucleophile as well as an electrophile....

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  3. CH(2)=CH^(-) is a better nucleophile than HC -= C^(-). Explain.

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  4. CH(2)=CH^(-) is more basic than HC -= C^(-). Explain why ?

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  5. Write the resonance structures of aniline and explain which one is the...

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  6. Arrange the following : (i) -NO(2), -COOH, -F, -CN, -I, in decreasin...

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  7. Arrange the following : (i) C(6)H(5)overset(*)(C)HCH(3), C(6)Hoverse...

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  8. When do we use a fine paper or hot water funnel for filtration ?

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  9. How will you purify a liquid having non-volatile impurities ?

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  10. How will you separate a mixture of urea and sodium chloride ?

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  11. How will you purify essential oils ?

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  12. How will you separate a mixture of o-nitrophenol and p-nitropheonol ?

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  13. Name two methods which can be safely used to purify aniline.

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  14. What type of compounds are purified by sublimation ?

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  15. How will you separate iodine from sodium chloride ?

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  18. Define the term 'elution' as applied to column chromatography.

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  20. Name two compounds which do not contain halogens but give positive Bei...

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