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Write the tautomers of (i) ethyl acetoac...

Write the tautomers of (i) ethyl acetoacetate and (ii) acetylacetone. Explain why the latter has higher percentage of enol than the former.

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The enolic form of ethyl acetoacetate as below has

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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Additional Questions (Short Answer Questions)
  1. Pick up the error an write the correct IUPAC names for the following. ...

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  2. Explain: (i) position isomerism (ii) functional isomerism giving one e...

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  3. Write the tautomers of (i) ethyl acetoacetate and (ii) acetylacetone. ...

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  4. Explain the following with one example in each case. (i) Homolytic f...

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  5. What are electrophiles and nucleophiles ? Explain with examples.

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  6. Explain inductive and electromeric effect with examples.

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  7. What is resonance? How does resonance explain that all the carbon-carb...

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  8. Spectroscopic measurements indicate that the two oxygen atoms of sodiu...

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  9. What is resonance effect ? What are its various types ? In what respec...

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  10. Camment upon the statement : 'Usual order of inductive effects of the ...

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  11. Explain hyperconjugation effect.

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  12. How does hyperconjugation effect explain the stability of alkenes ?

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  13. What are carbocations ? Discuss their various types.

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  14. Give two methods of preparation of carbocations.

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  15. Discuss the configuration of carbocations.

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  16. What are reactive intermediates ? How are they generated by bond fissi...

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  17. How an inductive and hyperconjugation effects the stability of primary...

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  18. What are carbanions ? Discuss their configuration.

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  19. Give two methods of preparation of carbanions.

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  20. Discuss the stability of carbanions on the basis of inductive effects.

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