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The correct stability order for the foll...

The correct stability order for the following species is

A

`(II) gt (IV) gt (I) gt (III)`

B

`(I) gt (II) gt (III) gt (IV)`

C

`(II) gt (I) gt (IV) gt (III)`

D

`(I) gt (III) gt (II) gt (IV)`

Text Solution

Verified by Experts

The correct Answer is:
D

Carbocation (I) is stabilized by +R - effect of O as well as +I -effect of two `CH_(3)` groups , carbocation (II) is stabilized by +I -effect of `CH_(3)` and `CH_(2)CH(CH_(3))_(2)` groups l carbocation (III) is stabilzes by +R effect of O and +I effect of one `CH_(3)` group while carbocation (IV) is stabilized by +I-effect of `CH_(2)CHCH(CH_(3))_(2)` group. Thus, decreasing order of stability of these carbocations is : `I gt III gt II gt IV`.
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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Competition Focus (Jee (Main and Advanced)/Medical Entrance) I. Multiple choice Questions (With One Correct Answer)
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  8. The order of stability of the following carbocations is underset(I)(...

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  9. the ascending order of stability of the carbanion CH(3)(P),C(6)H(5)ove...

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  10. Arrange the carbanions, (CH(3))(3)bar(C),bar(C)Cl(3),(CH(3))(2)bar(C)H...

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  11. The stability of carbanions in the following. (i) RC -= C^(Θ) (ii)...

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  12. The order of the base strength of the compounds (iii) NH(2)^(...

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  13. Which of the following compounds prossesses the C-H bonds with the low...

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  15. The increasing order of stability of the following free radicals is :

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  19. For the following reactions: CH(3)CH(2)CH(2)Br + KOH rarr CH(3)CH=C...

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