Home
Class 11
CHEMISTRY
Consider the following carbocations I ...

Consider the following carbocations
I `overset(+)underset((CH_(3))_(3)C CH_(2)`
II `(CH_(3))_(3)C^(+)`
III `{:(" " +),(CH_(3)CH_(2)CH_(2)):}`
IV `{:(" " +),(CH_(3)-CH-CH_(3)):}`
The correct order for the stability of the above carbocations is

A

`IV lt III lt II lt I`

B

`III lt IV lt I lt II`

C

`I lt III lt IV lt II`

D

`II lt IV lt III lt I`

Text Solution

Verified by Experts

The correct Answer is:
C

`(CH_(3))_(3)overset(+)(C)` (II) is stabilized by nine, `CH_(3)overset(+)(C)HCH_(3)(IV)` is stabilized by six, `CH_(3)CH_(2)CH_(2)^(+)` (III) is stabilized by two while `(CH_(3))_(3)C CH_(2)^(+)` (I) has no hyperconjugation structure. Therefore, II is the most stable, followed IV, then by III while I is the least stable. Thus, option (c) is correct.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES

    PRADEEP|Exercise Competition Focus (Jee (Main and Advanced)/Medical Entrance) II. Multiple Choice Questions (with one or more than one correct answers)|8 Videos
  • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES

    PRADEEP|Exercise Competition Focus (Jee (Main and Advanced)/Medical Entrance) III. Multiple Choice Questions (Comprehension)|12 Videos
  • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES

    PRADEEP|Exercise Analytical Questions and Problems with Answers/Solutions (Problems)|4 Videos
  • HYDROGEN

    PRADEEP|Exercise COMPETITION FOCUS (Assertion-Reason Type Questions) Type 2|15 Videos
  • P-BLOCK ELEMENTS (NITROGEN FAMILY)

    PRADEEP|Exercise Competition focus jee(main and advanced)/ medical entrance special) (VIII. Assertion-Reason Type Questions)|10 Videos

Similar Questions

Explore conceptually related problems

Consider the following carbocations, undersetI((CH_3)_3C overset+CH_2), underset(II)((CH_3)_3C^(+)), CH_(3)underset(III)CH_(2)overset(+)CH_(2), CH_(3)underset(IV)overset(+)CH-CH_(3) The correct order for the stability of the above carbocations is

Consider the following carbocation: (i) Cl_(3)overset(+)C (ii) Cl_(2)overset(+)CH , (iii) Cloverset(+)CH_(2) , (iv) overset(+)CH_(3)

Increasing order of the following stability is : CH_(3)underset((I))CH=CH_(3) CH_(3)underset((II))CH_(2)CH=CH_(2) (CH_(3))_(3)underset((IV))C CH=CH_(2)

The stability order in the following carbocations, CH_(3)CH_(2)^(+)"(I), "(CH_(3))_(2)overset(+)CH"(II), "(CH_(3))_(3)C^(+)"(III) "overset(+)CH_(3)"(IV)" is :

The order of stability of the following carbocations underset((I))(CH_(2)=overset(+)(C)H-CH_(2)) , underset((II))(CH_(3)-CH_(2)-overset(+)(C )H_(2))

Determine the stability order of given carbocations : underset(i.)(CH_(3)-CH_(2)^(+)) underset(ii.)(CH_(2)=CH^(+))

Which of the following carbocation is most stable ? (a) (CH_(3))_(3)C.overset(+)CH_(2) (b) (CH_(3))_(3)overset(+)C (c) CH_(3)CH_(2)overset(+)CH_(2) (d) CH_(3)overset(+)CHCH_(2)CH_(3)

PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Competition Focus (Jee (Main and Advanced)/Medical Entrance) I. Multiple choice Questions (With One Correct Answer)
  1. The decreasing order of stability of the carbonium ions C(6)H(5)CH(2...

    Text Solution

    |

  2. In the following carbocation, H//CH(3) that is most likely to migrate ...

    Text Solution

    |

  3. Consider the following carbocations I overset(+)underset((CH(3))(3)C...

    Text Solution

    |

  4. The order of stability of the following carbocations is underset(I)(...

    Text Solution

    |

  5. the ascending order of stability of the carbanion CH(3)(P),C(6)H(5)ove...

    Text Solution

    |

  6. Arrange the carbanions, (CH(3))(3)bar(C),bar(C)Cl(3),(CH(3))(2)bar(C)H...

    Text Solution

    |

  7. The stability of carbanions in the following. (i) RC -= C^(Θ) (ii)...

    Text Solution

    |

  8. The order of the base strength of the compounds (iii) NH(2)^(...

    Text Solution

    |

  9. Which of the following compounds prossesses the C-H bonds with the low...

    Text Solution

    |

  10. Most stable radical is

    Text Solution

    |

  11. The increasing order of stability of the following free radicals is :

    Text Solution

    |

  12. Arrange the following free radiacals in order of decreasing stability....

    Text Solution

    |

  13. The order of decreasing ease of abstraction of hydrogen atoms in the f...

    Text Solution

    |

  14. The reaction of methyl trichloroacetate (Cl(3)"CC"O(2)Me) with sodium ...

    Text Solution

    |

  15. For the following reactions: CH(3)CH(2)CH(2)Br + KOH rarr CH(3)CH=C...

    Text Solution

    |

  16. An alkyne combines with a conjugated diene to give an unconjugated cyc...

    Text Solution

    |

  17. How will you purify an impure sample of (i) Camphor (ii) aniline ?

    Text Solution

    |

  18. The best method for the separation of naphthalene and benzoic acid fro...

    Text Solution

    |

  19. A miscible mixture of C(6)H(6)+CHCl(3) can be separated by

    Text Solution

    |

  20. If the boiling point difference between the two liquids is not musch t...

    Text Solution

    |