The reaction of methyl trichloroacetate ...

The reaction of methyl trichloroacetate `(Cl_(3)"CC"O_(2)Me)` with sodium methoxide (NaOMe) generates :

A

carbocation

B

carbene

C

carbanion

D

carbon radical

Text Solution

Verified by Experts

The correct Answer is:

B

A carbene, i.e., dichlorocarbene is generated according to the following mechanism.

Promotional Banner

Promotional Banner

Topper's Solved these Questions

ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES
PRADEEP|Exercise Competition Focus (Jee (Main and Advanced)/Medical Entrance) II. Multiple Choice Questions (with one or more than one correct answers)|8 Videos
ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES
PRADEEP|Exercise Competition Focus (Jee (Main and Advanced)/Medical Entrance) III. Multiple Choice Questions (Comprehension)|12 Videos
ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES
PRADEEP|Exercise Analytical Questions and Problems with Answers/Solutions (Problems)|4 Videos
HYDROGEN
PRADEEP|Exercise COMPETITION FOCUS (Assertion-Reason Type Questions) Type 2|15 Videos
P-BLOCK ELEMENTS (NITROGEN FAMILY)
PRADEEP|Exercise Competition focus jee(main and advanced)/ medical entrance special) (VIII. Assertion-Reason Type Questions)|10 Videos

Similar Questions

Explore conceptually related problems

The reaction of p-nitrochlorobenzene with sodium methoxide to form p-nitroanisole occurs by _____reaction.

The S_(N)2 reaction of 1-chloro-3-methylbutane with sodium methoxide is relatively slow , but can be accelerated by the addition of a small amount of Nal . How is this catalysis best explained ?

Reaction of t-butyl bromide with sodium methoxide produces

The reaction of ethyl methyl ketone with Cl_(2)//"excess" OH^(-) gives the following major product

Reaction of t- butyl bromide with sodium methoxide produces

Assertion. t -Buty 1 Methyl ether is not prepared by rthe reaction of t- buty 1 bromide with sodium methoxide. Reason: Sodium methoxide is a strong nucleophile.

When methyl iodide is heated with sodium methoxide , it forms.

PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Competition Focus (Jee (Main and Advanced)/Medical Entrance) I. Multiple choice Questions (With One Correct Answer)

Arrange the following free radiacals in order of decreasing stability....
Text Solution
|
The order of decreasing ease of abstraction of hydrogen atoms in the f...
Text Solution
|
The reaction of methyl trichloroacetate (Cl(3)"CC"O(2)Me) with sodium ...
Text Solution
|
For the following reactions: CH(3)CH(2)CH(2)Br + KOH rarr CH(3)CH=C...
Text Solution
|
An alkyne combines with a conjugated diene to give an unconjugated cyc...
Text Solution
|
How will you purify an impure sample of (i) Camphor (ii) aniline ?
Text Solution
|
The best method for the separation of naphthalene and benzoic acid fro...
Text Solution
|
A miscible mixture of C(6)H(6)+CHCl(3) can be separated by
Text Solution
|
If the boiling point difference between the two liquids is not musch t...
Text Solution
|
The distillation technique most sited for separating glycerol from spe...
Text Solution
|
In steam distillation of toluene , the pressure of toluene in vapour i...
Text Solution
|
The most suitable method of separation of a 1:1 mixture of o- and p- n...
Text Solution
|
The separation of the constituents of a mixture by column chromatograp...
Text Solution
|
Paper chromatography has following mobile and stationary phases respec...
Text Solution
|
The elution sequence of a mixture of compounds containing chlorobenzen...
Text Solution
|
An organic compound which produces a bluish green colored flame on hea...
Text Solution
|
During the fusion of an organic compound with sodium metal, nitrogen o...
Text Solution
|
In the Lassaigne's test for the detection of nitrogen in an organic co...
Text Solution
|
The LaSSaigen's extract is boiled with conc. HNO(3) while testing for...
Text Solution
|
Lassaigne's test (with silver nitrate) is commonly used to detect halo...
Text Solution
|