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How many of the following are heterocycl...

How many of the following are heterocyclic aromatic compounds ?
benzene, cyclopentadiene, oxirane, tetrahydrofuran, naphthalene, cyclopentane, tropolone, azulene, diphenyl.

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To determine how many of the given compounds are heterocyclic aromatic compounds, we need to analyze each compound based on the definitions of heterocyclic and aromatic compounds. ### Step-by-Step Solution: 1. **Benzene**: - Benzene is a cyclic compound consisting only of carbon atoms. - It is aromatic due to its planar structure and the delocalization of 6 π electrons (follows Huckel's rule). - **Conclusion**: Not heterocyclic (homocyclic). 2. **Cyclopentadiene**: - Cyclopentadiene is a five-membered ring with two double bonds. - It is not planar due to sp³ hybridization of one of the carbons, and it does not have delocalized π electrons. - **Conclusion**: Not aromatic and not heterocyclic. 3. **Oxirane**: - Oxirane (ethylene oxide) is a three-membered ring containing one oxygen atom. - It is not aromatic because it does not have delocalized π electrons. - **Conclusion**: Heterocyclic but not aromatic. 4. **Tetrahydrofuran**: - Tetrahydrofuran is a five-membered ring with one oxygen atom. - It is not aromatic because it does not have delocalized π electrons. - **Conclusion**: Heterocyclic but not aromatic. 5. **Naphthalene**: - Naphthalene consists of two fused benzene rings. - It is aromatic due to delocalized π electrons (10 π electrons). - **Conclusion**: Not heterocyclic (homocyclic). 6. **Cyclopentane**: - Cyclopentane is a five-membered ring consisting only of carbon atoms. - It is not aromatic because it is not planar and does not have delocalized π electrons. - **Conclusion**: Not heterocyclic (homocyclic). 7. **Tropolone**: - Tropolone has a seven-membered ring with one oxygen atom and three double bonds. - It is aromatic due to the delocalization of π electrons (6 π electrons). - **Conclusion**: Not heterocyclic (homocyclic). 8. **Azulene**: - Azulene consists of two fused rings (5-membered and 7-membered) and has a total of 10 π electrons. - It is aromatic due to delocalization. - **Conclusion**: Not heterocyclic (homocyclic). 9. **Diphenyl**: - Diphenyl consists of two benzene rings. - It is aromatic due to delocalized π electrons (12 π electrons). - **Conclusion**: Not heterocyclic (homocyclic). ### Summary of Findings: - Heterocyclic aromatic compounds found: **0** - Compounds that are heterocyclic but not aromatic: **Oxirane, Tetrahydrofuran** (2 total) - Compounds that are neither heterocyclic nor aromatic: **Benzene, Cyclopentadiene, Naphthalene, Cyclopentane, Tropolone, Azulene, Diphenyl** (7 total) ### Final Answer: **Total number of heterocyclic aromatic compounds: 0**

To determine how many of the given compounds are heterocyclic aromatic compounds, we need to analyze each compound based on the definitions of heterocyclic and aromatic compounds. ### Step-by-Step Solution: 1. **Benzene**: - Benzene is a cyclic compound consisting only of carbon atoms. - It is aromatic due to its planar structure and the delocalization of 6 π electrons (follows Huckel's rule). - **Conclusion**: Not heterocyclic (homocyclic). ...
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Knowledge Check

  • Which one of the following is the heterocyclic aromatic compounds?

    A
    Pyrene
    B
    Thiophene
    C
    Phenol
    D
    Aniline
  • Which of the following is not a heterocyclic aromatic compound?

    A
    (1) Pyridine
    B
    (2) Pyrrolidine
    C
    (3) Pyrrole
    D
    (4) Furan
  • Which of the following heterocyclic compound/s might be aromatic?

    A
    B
    C
    D