Home
Class 11
CHEMISTRY
Suggest a route to prepare ethyl hydroge...

Suggest a route to prepare ethyl hydrogensulphate `(CH_(3)-CH_(2)-OSO_(2)-OH)` starting from ethanol `(C_(2)H_(5)OH)` .

Text Solution

Verified by Experts

When ethanol is heated with conc. `H_2SO_4` at 383 K (i.e. , `110^@` C), ethyl hydrogen sulphate is formed.
`H_2SO_4 to H^(+) + underset"Hydrogen sulphate ion"(.^-OSO_2OH)`

Temperature should not be allowed to rise above 383 K, otherwise diethyl ether will be obtained at 413 K or ethane at 433-443 K.
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBONS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MATCHING TYPE QUESTIONS)|4 Videos
  • HYDROCARBONS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (ASSERTION AND REASON TYPE QUESTIONS)|4 Videos
  • HYDROCARBONS

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE CHOICE -II)|9 Videos
  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise Competition Focus (Jee(Main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS (TYPE - II)|10 Videos
  • HYDROGEN

    PRADEEP|Exercise COMPETITION FOCUS (Assertion-Reason Type Questions) Type 2|15 Videos

Similar Questions

Explore conceptually related problems

CH_(3)COOH + C_(2)H_(5)OH overset(X) to CH_(3)COOC_(2)H_(5) +H_(2)O ,X is

Complete the reaction: CH_(3)-CH_(2)C-=N overset(Na(Hg) // C_(2)H_(5)OH)(to) ?

Test to differentiate between ethanol (CH_(3)CH_(2)OH) and phenol (Ph-OH) is /are

CH_(3)OH+C_(2)H_(5)OH overset(H^(o+))rarr Products

Arrange the following in decreasing order of solubility in water (i) CH_(3)CH_(2)OH (ii) CH_(3)OH (iii) C_(6)H_(5)CH_(2)OH .

Suggest the possible pathways of coverting (R)-n-C_(3)H_(7)CH(OH)CH_(3)(A) into its ethyl ether n-C_(3)H_(7)CH(OC_(2)H_(5))CH_(3) using Fischer projections and give their R, S designations.

PRADEEP-HYDROCARBONS-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (SHORT ANSWER QUESTIONS)
  1. Why do alkenes prefer to undergo electrophilec addition reaction while...

    Text Solution

    |

  2. Alkynes on reduction with sodium in liquid ammonia form trans alkenes....

    Text Solution

    |

  3. Rotation around carbon-carbon single bond of ethane is not completely ...

    Text Solution

    |

  4. Draw Newman and sawhorse projections for the eclipsed and staggered co...

    Text Solution

    |

  5. The intermediate carbocation formed in the reactions of HI,HBr, and HC...

    Text Solution

    |

  6. What will be the product obtained as a result of the following reactio...

    Text Solution

    |

  7. How will you convert benzene into: (i) p-nitrobromobenzene (ii) ...

    Text Solution

    |

  8. Arrange the following set of compounds in the order of their decreasin...

    Text Solution

    |

  9. Despite their-I effect, halogens are o- and p- directing in haloarenes...

    Text Solution

    |

  10. Why does presence of a nifro group make the benzene ring less reactive...

    Text Solution

    |

  11. Suggest a route for the preparation of nitrobenzene starting from acet...

    Text Solution

    |

  12. Predict the major product(s) of the following reactions and explain th...

    Text Solution

    |

  13. Nucleophiles and electrophiles are reaction intermediates having elect...

    Text Solution

    |

  14. The relative reactivity of 1^(@), 2^(@) and 3^(@) hybrogen's towards c...

    Text Solution

    |

  15. Write the structures and names of products obtained in the reactions o...

    Text Solution

    |

  16. Write hydrocarbon radicals that can be formed as intermediates during ...

    Text Solution

    |

  17. An alkane C(8)H(18) is obtained as the only product on subjecting a pr...

    Text Solution

    |

  18. The ring systems having following characteristics are aromatic. (i) ...

    Text Solution

    |

  19. Which of the following compounds are aromatic according to Huckle's ru...

    Text Solution

    |

  20. Suggest a route to prepare ethyl hydrogensulphate (CH(3)-CH(2)-OSO(2)-...

    Text Solution

    |