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The reaction of C6H5CH=CHCH3 with HBr pr...

The reaction of `C_6H_5CH=CHCH_3` with HBr produces

A

`C_6H_5CH_2CH_2CH_2Br`

B

C

`C_6H_5undersetunderset"Br"|CHCH_2CH_3`

D

`C_6H_5CH_2undersetunderset"Br"|CH_2CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of `C_6H_5CH=CHCH_3` (which is styrylpropane) with HBr, we can follow these steps: ### Step 1: Identify the Structure The compound `C_6H_5CH=CHCH_3` can be represented as: - A phenyl group (C6H5) attached to a double bond (CH=CH) followed by a methyl group (CH3). ### Step 2: Understand the Reaction with HBr When HBr reacts with alkenes, it adds across the double bond. The addition occurs through a mechanism that involves the formation of a carbocation intermediate. ### Step 3: Determine the Site of Protonation In this case, the double bond is between the second and third carbon atoms (C2 and C3). HBr will first protonate one of the carbons in the double bond. The more stable carbocation will form, which is determined by the stability of the resulting carbocation. ### Step 4: Analyze Carbocation Stability The possible carbocations that can form are: 1. Protonation at C2 (leading to a secondary carbocation). 2. Protonation at C3 (leading to a primary carbocation). Since secondary carbocations are more stable than primary carbocations due to greater hyperconjugation and inductive effects, the proton will add to C2. ### Step 5: Form the Carbocation After protonation, we will have the following structure: - The carbocation will be at C2, which is attached to the phenyl group (C6H5) and has a positive charge. ### Step 6: Nucleophilic Attack by Bromide Ion The bromide ion (Br-) will then attack the carbocation at C2, leading to the formation of the final product. ### Step 7: Write the Final Product The final product of the reaction will be: - `C6H5CHBrCH2CH3` (where Br is attached to C2). ### Final Answer The reaction of `C_6H_5CH=CHCH_3` with HBr produces `C6H5CHBrCH2CH3`. ---

To solve the question regarding the reaction of `C_6H_5CH=CHCH_3` (which is styrylpropane) with HBr, we can follow these steps: ### Step 1: Identify the Structure The compound `C_6H_5CH=CHCH_3` can be represented as: - A phenyl group (C6H5) attached to a double bond (CH=CH) followed by a methyl group (CH3). ### Step 2: Understand the Reaction with HBr When HBr reacts with alkenes, it adds across the double bond. The addition occurs through a mechanism that involves the formation of a carbocation intermediate. ...
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PRADEEP-HYDROCARBONS-Competition Focus (JEE(main and advanced)/Medical Entrance) I. MULTIPLE CHOICE QUESTIONS
  1. The compound that will react most readily with gaseous bromine has the...

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  2. 3-Phenylpropene on reaction with HBr gives (as major product)

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  3. The reaction of C6H5CH=CHCH3 with HBr produces

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  4. H3C-undersetunderset(CH3)|CH-CH=CH2+HBr to A A (predominantly ) is

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  5. HBr reacts with CH2=CH-OCH3 under anhydrous condditions at room temper...

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  6. The additon of HBr to 2-pentene gives

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  7. In the reaction with HCl, an alkene reacts in accordance with Markowni...

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  8. In which of the following can peroxide effect operate ?

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  9. The alkene that will give the same product with HBr in the presence as...

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  10. CH3CH2-CH=CH2+HBr overset"ROOR"to underset"Major"[X]+underset"Minor"[Y...

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  11. The reaction of propene with HBr in presence of peroxide proceeds thro...

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  12. When 3-phenylpropene reacts with HBr in the presence of peroxide, the ...

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  13. The major product obtained by the addition reaction of HBr to 4-methyl...

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  14. Observe the following reactions and predict the nature of A and B

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  15. In presence of peroxide, hydrogen chloride and hydrogen iodide do not ...

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  16. Acid catalysed hydration of alkene is an example for

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  17. 2,3-Dimethyl-2-butene can be prepared by heating which of the followin...

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  18. Acid catalysed hydration of alkenes except ethene leads to the formati...

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  19. 2-Phenyl propene on acidic hydration gives ,

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  20. Among the alkenes, which one produces tertiary butyl alcohol on acid h...

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