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Acid catalysed hydration of alkenes exce...

Acid catalysed hydration of alkenes except ethene leads to the formation of

A

primary alcohol

B

secondary or tertiary alcohols

C

mixture of primary and secondary alcohols

D

mixture of secondary and tertiary alcohols

Text Solution

Verified by Experts

The correct Answer is:
B

Ethene gives `1^@` alcohol (ethanol) , propene gives `2^@` alcohol while 2-methylpropene gives `3^@` alcohol.
`underset"Ethene"(CH_2=CH_2)underset((ii)H_3O^+)overset((i)Conc. H_2SO_4)to underset"Ethanol"(CH_3CH_2OH)`
`underset"Propene"(CH_3-CH=CH_2)underset((ii)H_3O^+)overset((i)Conc. H_2SO_4)to underset(2^@ "Alcohol")(CH_3-CHOH-CH_3)`
`underset"2-Methylpropene"(CH_3-oversetoverset(CH_3)|C=CH_2)underset((ii)H_3O^+)overset(Conc. H_2SO_4)to underset(3^@ "Alcohol")((CH_3)_3COH)`
Thus , either `2^@` or `3^@` alcohol is formed.
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PRADEEP-HYDROCARBONS-Competition Focus (JEE(main and advanced)/Medical Entrance) I. MULTIPLE CHOICE QUESTIONS
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  4. 2-Phenyl propene on acidic hydration gives ,

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  6. Propene on reaction with chlorine water gives

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  7. On ozonolysis , one mole of a hydrocarbon produces two molecules of et...

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  8. An alkene on reductive ozonolysis gives two molecules of CH(2)(CHO)(2...

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  9. Which of the compounds with molecular formula C(5)H(10)yields acetone ...

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  11. 5-oxohexanal is obtained by ozonolysis of:

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  12. Ozonolysis of an alkene produces only one dicarbonyl compound. The str...

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  13. The major products obtained during ozonolysis of 2,3-dimethyl-1-butene...

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  14. Oxidation of an alkene (X) gives a diol. Further oxidation gives a dik...

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  15. Select the reagent for the following reaction,

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  16. Among the following , the alkene on ozonolysis giving rise to only on...

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  17. Products of the following reaction Me2C=CHCH3 underset((ii)(CH3)2S)ove...

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  18. One mole of a symmetrical alkene on ozonolysis gives two moles of an a...

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  19. Ozonolysis of an organic compound gives formaldehyde as one of the pro...

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  20. Which compound would give 5-keto-2-methylhexanal on ozonolysis ?

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