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What is the electrophile when RCl + AlCl...

What is the electrophile when RCl + `AlCl_3` are used in Friedel-Crafts reaction ?

A

`Cl^+`

B

`AlCl_4^-`

C

`R^+`

D

`AlCl_2^+`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the electrophile in the Friedel-Crafts reaction involving RCl and AlCl3, we can follow these steps: ### Step 1: Understand the Reaction Components In the Friedel-Crafts reaction, we are using RCl (an alkyl chloride) and AlCl3 (aluminum chloride). ### Step 2: Identify the Role of AlCl3 AlCl3 acts as a Lewis acid in this reaction. It has a strong tendency to accept electrons due to its electron-deficient nature. When AlCl3 interacts with RCl, it forms a complex. ### Step 3: Formation of the Electrophile When RCl reacts with AlCl3, the aluminum chloride coordinates with the chlorine atom of RCl. This results in the formation of a carbocation (R+) and a complex ion (AlCl4-). The reaction can be represented as follows: \[ RCl + AlCl_3 \rightarrow R^+ + AlCl_4^- \] ### Step 4: Identify the Electrophile In this reaction, the species R+ (the carbocation) is positively charged and is electron-deficient. Therefore, it acts as the electrophile in the Friedel-Crafts reaction. ### Conclusion The electrophile formed when RCl and AlCl3 are used in the Friedel-Crafts reaction is R+. ### Final Answer The electrophile is R+. ---
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