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Statement-1. Acetylene is more reactive ...

Statement-1. Acetylene is more reactive than ethylene towards electrophilic addition reactions
Statement-2. Acetylene contains two `pi`-bonds

A

Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True , Statement-2 is not a correct explanation for Statement-1

C

Statement- 1 is True, Statement-2 is False

D

Statement-1 is False, Statement -2 is True

Text Solution

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The correct Answer is:
To determine the validity of the statements regarding the reactivity of acetylene and ethylene towards electrophilic addition reactions, let's analyze each statement step by step. ### Step 1: Understanding the Structures - **Acetylene (C2H2)** has a triple bond between the two carbon atoms, which consists of one sigma bond and two pi bonds. - **Ethylene (C2H4)** has a double bond between the two carbon atoms, consisting of one sigma bond and one pi bond. ### Step 2: Electrophilic Addition Mechanism - In electrophilic addition reactions, an electrophile (E+) attacks the electron-rich double or triple bond. - The more electron-rich the bond, the more reactive it is towards electrophiles. ### Step 3: Reactivity Comparison - Acetylene, with its triple bond (two pi bonds), has a higher electron density compared to ethylene, which has only one pi bond. - The presence of two pi bonds in acetylene makes it more reactive towards electrophilic addition reactions than ethylene, which has only one pi bond. ### Step 4: Analyzing Statement-1 - **Statement-1:** "Acetylene is more reactive than ethylene towards electrophilic addition reactions." - This statement is **True** because acetylene has a higher electron density due to the presence of two pi bonds, making it more reactive. ### Step 5: Analyzing Statement-2 - **Statement-2:** "Acetylene contains two pi bonds." - This statement is also **True** as acetylene indeed has two pi bonds in its triple bond structure. ### Conclusion Both statements are true: - Statement-1 is true because acetylene is more reactive than ethylene towards electrophilic addition reactions. - Statement-2 is true because acetylene contains two pi bonds. ### Final Answer - Statement-1: True - Statement-2: True ---

To determine the validity of the statements regarding the reactivity of acetylene and ethylene towards electrophilic addition reactions, let's analyze each statement step by step. ### Step 1: Understanding the Structures - **Acetylene (C2H2)** has a triple bond between the two carbon atoms, which consists of one sigma bond and two pi bonds. - **Ethylene (C2H4)** has a double bond between the two carbon atoms, consisting of one sigma bond and one pi bond. ### Step 2: Electrophilic Addition Mechanism - In electrophilic addition reactions, an electrophile (E+) attacks the electron-rich double or triple bond. ...
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PRADEEP-HYDROCARBONS-Competition Focus (JEE(main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS
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  5. Statement-1. The reaction of conc. HNO3 and conc. H2SO4 on nitrobenzen...

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  6. Statement-1. Toluene on sulphonation gives m-toluenesulfonic acid. ...

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  7. Assertion. Melting point of neopentane is higher than that of n- penta...

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  8. Assertion. Conformers are impractical to separate Reason. Conformer...

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  9. Assertion : Boiling points of cis-isomers are higher than trans - isom...

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  10. Assertion. Propene is more reactive than ethene towards electrophilic ...

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  12. Assertion. Propene reacts with hydrogen chloride in presence of organi...

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  13. Assertion. C-H bond in ethyne is shorter than C-H bonds in ethene. ...

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  14. Assertion. Calcium carbide on hydrolysis gives ethylene Reason. Cal...

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  15. Assertion. Acidity of the C-H bond decreases in the order: HC-=CH gt H...

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  16. Assertion. Acetylene reacts with sodamide te evolve H2 gas Reason. ...

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  17. Assertion : Acetylene on reacting with sodamide gives sodium acetylide...

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  18. Assertion. Addition of H2O to acetylene occurs in presence of dil. H2S...

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  19. Assertion. But 1-yne and but-2-yne can be distinguished by ammoniacal ...

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  20. Assertion. Alkynes are more reactive towards nucleophilic addition rea...

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