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Assertion. Propene is more reactive than...

Assertion. Propene is more reactive than ethene towards electrophilic addition reactions
Reason. Hyperconjugation effect of the `CH_3` group increases the electron density in the double bond

A

If both assertion and reason are true, and reason is the true explanation of the assertion.

B

If both assertion and reason are true, but reason is not the true explanation of the assertion.

C

If assertion is true, but reason is false.

D

If both assertion and reason are false

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Propene is more reactive than ethene towards electrophilic addition reactions." - **Explanation**: Electrophilic addition reactions involve the addition of an electrophile to a double bond. The reactivity of alkenes in these reactions is influenced by the stability of the carbocation intermediate formed during the reaction. ### Step 2: Analyze the Structure of Propene and Ethene - **Propene** has the structure CH3-CH=CH2, while **Ethene** has the structure CH2=CH2. - When an electrophile approaches, a carbocation is formed. In propene, the carbocation can be stabilized by hyperconjugation due to the presence of the CH3 group. ### Step 3: Stability of Carbocations - The stability of carbocations increases with the number of alkyl groups attached to the positively charged carbon. - In propene, the carbocation formed (if the electrophile adds to the terminal carbon) can be stabilized by three hyperconjugative interactions from the three hydrogen atoms of the CH3 group. - In contrast, the carbocation formed from ethene (if the electrophile adds to either carbon) has no alkyl groups to stabilize it. ### Step 4: Conclusion on Reactivity - Since propene forms a more stable carbocation than ethene, it follows that propene is more reactive towards electrophilic addition reactions. ### Step 5: Analyze the Reason The reason states that "Hyperconjugation effect of the CH3 group increases the electron density in the double bond." - **Explanation**: Hyperconjugation involves the delocalization of electrons from the adjacent C-H bonds to the empty p-orbital of the carbocation, which increases the electron density in the double bond and stabilizes the carbocation. ### Final Conclusion - Both the assertion and the reason are true. The reason correctly explains why propene is more reactive than ethene towards electrophilic addition reactions. ### Summary - **Assertion**: True - **Reason**: True - **Explanation**: The hyperconjugation effect of the CH3 group in propene increases the electron density in the double bond, making propene more reactive than ethene. ---
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