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Assertion. C-H bond in ethyne is shorter...

Assertion. C-H bond in ethyne is shorter than C-H bonds in ethene.
Reason. Carbon atom in ethene is sp hybridised while it is `sp^3` in ethyne.

A

If both assertion and reason are true, and reason is the true explanation of the assertion.

B

If both assertion and reason are true, but reason is not the true explanation of the assertion.

C

If assertion is true, but reason is false.

D

If both assertion and reason are false

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The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the C-H bond in ethyne (C2H2) is shorter than the C-H bond in ethene (C2H4). - Ethyne has a triple bond between the carbon atoms (C≡C), and each carbon is bonded to one hydrogen atom. - Ethene has a double bond between the carbon atoms (C=C), and each carbon is bonded to two hydrogen atoms. ### Step 2: Compare the C-H Bonds The bond length is influenced by the type of hybridization and the bond order: - In ethyne, the carbon atoms are sp hybridized, which means they have a higher s-character (50% s and 50% p). This results in stronger and shorter bonds. - In ethene, the carbon atoms are sp² hybridized (33% s and 67% p), which results in longer C-H bonds compared to ethyne. Thus, the assertion is correct: the C-H bond in ethyne is indeed shorter than in ethene. ### Step 3: Understand the Reason The reason states that the carbon atom in ethene is sp hybridized while it is sp³ in ethyne. - This statement is incorrect. In ethene, the carbon atoms are sp² hybridized, not sp hybridized. - In ethyne, the carbon atoms are sp hybridized. ### Step 4: Conclusion - The assertion is true: C-H bond in ethyne is shorter than in ethene. - The reason is false: the hybridization of carbon in ethene is sp², not sp. ### Final Answer The assertion is true, but the reason is false.

To solve the question, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the C-H bond in ethyne (C2H2) is shorter than the C-H bond in ethene (C2H4). - Ethyne has a triple bond between the carbon atoms (C≡C), and each carbon is bonded to one hydrogen atom. - Ethene has a double bond between the carbon atoms (C=C), and each carbon is bonded to two hydrogen atoms. ...
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