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H(α) line of Balmer series is 6500 Å . T...

`H_(α)` line of Balmer series is 6500 `Å` . The wave length of `H_(gamma)` is

A

4815 `Å`

B

4341`Å`

C

`7800Å`

D

`3800Å`

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The correct Answer is:
To find the wavelength of the H-gamma line in the Balmer series, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Balmer Series**: The Balmer series corresponds to electronic transitions in hydrogen where the electron falls to the n=2 energy level from higher energy levels (n=3, 4, 5, ...). The H-alpha line corresponds to the transition from n=3 to n=2, while the H-gamma line corresponds to the transition from n=5 to n=2. 2. **Identify the Given Information**: We know that the wavelength of the H-alpha line (n=3 to n=2) is given as 6500 Å (angstroms). 3. **Use the Rydberg Formula**: The formula to calculate the wavelength of the spectral lines in hydrogen is: \[ \frac{1}{\lambda} = R_z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant (approximately 109677 cm⁻¹ for hydrogen), \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. 4. **Set Values for H-gamma**: For H-gamma, \( n_1 = 2 \) and \( n_2 = 5 \). Plugging these values into the Rydberg formula gives: \[ \frac{1}{\lambda_{\gamma}} = R \left( \frac{1}{2^2} - \frac{1}{5^2} \right) \] 5. **Calculate the Right Side**: - Calculate \( \frac{1}{2^2} = \frac{1}{4} = 0.25 \) - Calculate \( \frac{1}{5^2} = \frac{1}{25} = 0.04 \) - So, \( \frac{1}{2^2} - \frac{1}{5^2} = 0.25 - 0.04 = 0.21 \) 6. **Substitute Rydberg Constant**: Now substituting the Rydberg constant: \[ \frac{1}{\lambda_{\gamma}} = 109677 \times 0.21 \] \[ \frac{1}{\lambda_{\gamma}} = 23030.17 \, \text{cm}^{-1} \] 7. **Find Wavelength**: To find \( \lambda_{\gamma} \): \[ \lambda_{\gamma} = \frac{1}{23030.17} \, \text{cm} \] \[ \lambda_{\gamma} \approx 0.0000434 \, \text{cm} \] 8. **Convert to Angstroms**: Since \( 1 \, \text{cm} = 10^{10} \, \text{Å} \): \[ \lambda_{\gamma} \approx 0.0000434 \times 10^{10} \, \text{Å} = 4340 \, \text{Å} \] ### Final Answer: The wavelength of the H-gamma line is approximately **4340 Å**. ---
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