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Calculate the average molar heat capaci...

Calculate the average molar heat capacity at constant volume of a mixture containing 2 moles of monoatomic and 3 moles of diatomic ideal gas.

A

R

B

2.1 R

C

3.2 R

D

4 R

Text Solution

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The correct Answer is:
To calculate the average molar heat capacity at constant volume (\(C_{V,\text{avg}}\)) of a mixture containing 2 moles of a monoatomic ideal gas and 3 moles of a diatomic ideal gas, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the number of moles and specific heat capacities:** - For the monoatomic gas: - Number of moles (\(n_1\)) = 2 - Molar heat capacity at constant volume (\(C_{V1}\)) = \(\frac{3}{2}R\) - For the diatomic gas: - Number of moles (\(n_2\)) = 3 - Molar heat capacity at constant volume (\(C_{V2}\)) = \(\frac{5}{2}R\) 2. **Use the formula for average molar heat capacity of the mixture:** \[ C_{V,\text{avg}} = \frac{n_1 C_{V1} + n_2 C_{V2}}{n_1 + n_2} \] 3. **Substitute the values into the formula:** \[ C_{V,\text{avg}} = \frac{(2 \cdot \frac{3}{2}R) + (3 \cdot \frac{5}{2}R)}{2 + 3} \] 4. **Calculate the contributions from each gas:** - Contribution from the monoatomic gas: \[ 2 \cdot \frac{3}{2}R = 3R \] - Contribution from the diatomic gas: \[ 3 \cdot \frac{5}{2}R = \frac{15}{2}R \] 5. **Combine the contributions:** \[ C_{V,\text{avg}} = \frac{3R + \frac{15}{2}R}{5} \] 6. **Convert \(3R\) into a fraction with a common denominator:** \[ 3R = \frac{6}{2}R \] Thus, \[ C_{V,\text{avg}} = \frac{\frac{6}{2}R + \frac{15}{2}R}{5} = \frac{\frac{21}{2}R}{5} \] 7. **Simplify the expression:** \[ C_{V,\text{avg}} = \frac{21R}{10} = 2.1R \] ### Final Answer: The average molar heat capacity at constant volume of the mixture is \(2.1R\). ---
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