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Give evidence to show that [Co(NH(3))(5)...

Give evidence to show that `[Co(NH_(3))_(5)Cl]SO_(4)` and `[Co(NH_(3))_(5)SO_(4)]Cl` exist as ionisation isomers.

Text Solution

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Ionization isomers have different type of anions on dissociation .
`[Co(NH_(3))_(5)Cl]SO_(4) iff [Co(NH_(3))_(5)Cl]^(2+)+SO_(4)^(2-)`
`[Co(NH_(3))_(5)SO_(4)]Cl iff [Co(NH_(3))_(5)SO_(4)]^(+)+Cl^(-)`
As these compound are giving different ions in the solution , these are ionisation isomers of each others .
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