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[Co(NH(3))(5)NO(2)]SO(4) shows...

`[Co(NH_(3))_(5)NO_(2)]SO_(4)` shows

A

Ionisation isomerism

B

Coordination isomerism

C

Linkage isomerism

D

Position isomerism

Text Solution

Verified by Experts

The correct Answer is:
A, C
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[Cr(NH_(3))_(5)NO_(2)]SO_(4) and [Cr(NH_(3))_(5)ONO]SO_(4) are related to each other as: .

What type of isomers are the following (a) [Mn(CO)_(5)(SCN)] and [Mn(CO)_(5)(NCS)] (b) [Co(en)-(3)][Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)] ( c) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)] NO_(3) (d) [Co(py)_(2)(H_(2)O)_(2)CI_(2)]CI and [Co(py)_(2)(H_(2)O)CI_(3)]H_(2)O (II) (a) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2))][Cr(NH_(3))_(2)(CN)_(4)] (b) [Pt(NH_(3))_(4)Br_(2)]CI_(2) and [Pt(NH_(3))_(4)CI_(2)]Br_(2) .

What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

What type of isomers are the following : (i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS] (ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)] (iii) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)]NO_(3) (iv) [Co(H_(2)O)_(2)Cl_(2)(py)_(2)]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O

The IUPAC name for [Co(NH_(3))_(5) (ONO)] SO_(4) is

0.001 mol of Co(NH_(3))_(5)(NO_(3))(SO_(4)) was passed through a cation exchanger and the acid coming out of it required 20 ml of 0.1 M NaOH for neutralisation. Hence, the complex is

IUPAC name [Co(NH_(3))_(5)(NO_(2))]Cl_(2) is

0.001 mol of Cr(NH_(3))_(5)(NO_(3))(SO_(4)) was passed through a cation exchanger the acid coming out of it reguired 20mL of 0.1M NaoH for netralisation Hence the complex is [Cr(NH_(3))_(5)SO_(4)]NO_(3) (b) [Cr(NH_(3))_(5)NO_(3)]SO_(4) (c ) [Cr(NH_(3))_(5)](SO_(4))(NO_(3) (d) [Co(NH_(3))_(5)Br]SO_(4) .

[Co(NH_(3))_(5)SO_(4)]Br and [Co(NH_(3))_(5)Br]SO_(4) shown _________isomerism .