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Choose the incorrect regarding stability...

Choose the incorrect regarding stability
(a) `[Fe("phen")_(3)]^(+2) gt [Fe("phen")_(3)]^(+3)`
(b) `[Fe(CN)_(6)]^(-4) gt [Fe(CN)_(6)]^(-3)`
(c) `Fe("dipy")_(3)^(+3) gt Fe("dipy")_(3)^(+2)`

A

a,b

B

b,c

C

a,c

D

a,b,c

Text Solution

Verified by Experts

The correct Answer is:
A
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K_(3)[Fe(CN)_(6)]+FeCl_(3) to Fe[Fe(CN)_(6)]

[Fe(H_(2)O)_(6)]^(3+) and [Fe(CN)_(6)]^(3-) differ in

K_(3)[Fe(CN)_(6)]+FeCl_(2) to Fe_(3)[Fe(CN)_(6)]_(2)darr

The [Fe(CN)_(6)]^(3-) complex ion :

Fe(CN)_(2)darr+KCN to K_(3)Fe(CN)_(6)