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(CH(3))(3)-C-MgCl on reaction with D(2)O...

`(CH_(3))_(3)-C-MgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3) CD`

B

`(CH_(3))_(3) COD`

C

`(CD_(3))_(3) CD`

D

`(CD_(3))_(3)COD`

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(CH_(3))_(3)CMgBr on reaction with D_(2)O produces :

Me_3 C-MgCl on reaction with D_2 O produces :

(CH_3)_3CMgCl on reaction with D_2O produces

Identify the total number of following compounds which liberate CH_(4) gas on reaction with CH_(3)MgCl (i) H_(2)O (ii) CH_(2)=CH_(2) (iii) Me-C-=C-H

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

AAKASH INSTITUTE-HALOALKANES AND HALOARENES -Assignment (Section - A ) ( Competition Level Question )
  1. Which of the following is used as fire extinguisher under the na...

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  2. Which of the following is known as freon which is used as a refrigeran...

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  3. (CH(3))(3)-C-MgCl on reaction with D(2)O produces

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  4. Which of the following is known as freon 12 ?

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  5. ( R ) -2-Iodobutane is treated with Nal in acetone and allowed to sta...

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  6. Which of the following halogen exchange reaction will occur in aceto...

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  7. The intermediate during the addition of HCl to propene in the presence...

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  8. The addition of HBr is the easiest with

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  9. The reaction of propene with HOCl proceeds via the addition of :

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  10. which is more reactive nucleophile in polar protic solvent ?

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  11. Which is more reactive nucleophile in polar aprotic solvent ?

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  12. CH(2) = CH - NO(2) + HBr to P, The major product P is

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  13. CH(3) -CH =CH(2) + HOBr to P, The major product P is

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  14. Complete the following reaction

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  15. The reaction goes through

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  16. Complete the following reaction

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  17. Which of the following solvent is suitable for S(N)1 reaction ?

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  18. The order of E(2) elimination for alkyl halide is

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  19. Complete the following reaction

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  20. Complete the following reaction

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