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For the galvanic cell: Ag(s) | AgBr(aq...

For the galvanic cell:
`Ag(s) | AgBr(aq) | Br^(-)(aq) || Cl^(-)(aq)| AgCl(s)| Ag(s)`
the value of `E_(cell)^(@)` at 298 K:
[Given : `K_(sp)` of AgCl `=2 xx 10^(-10)`.
`K_(sp)` of AgBr `= 4 xx 10^(-13) = (2.303R xx 298)/(F) = 0.06`, log 2 = 0.3]`

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The overall reaction electrochemical cell at 298K. Ag(s)|AgI(s)|I^(-)(aq)||Cl^(-)(aq)|Hg_(2)Cl_(2)|Hg(l)|Pt(s) [Given: E_(Cl^(-)|Hg_(2)Cl_(2)|Hg)^(@)=0.26V. E_(Ag^(+)|Ag)^(@)=0.8V . K_(sp)(Agl)=10^(-16) and (2.303RT)/(F)=0.06 ] At equilibrium ratio of ([Cl^(-)])/([I^(-)]) in the above cell will be:

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