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Account for the following : The exp...

Account for the following :
The experimentally determined N_F bond length in ` NF_(3)` is greater than the sum of the sigle
covalent radii of N and F.

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AI Generated Solution

To account for the observation that the experimentally determined N-F bond length in NF₃ is greater than the sum of the single covalent radii of nitrogen (N) and fluorine (F), we can analyze the factors influencing bond lengths in covalent compounds. ### Step-by-Step Solution: 1. **Understanding Covalent Radii**: - Covalent radii are the measure of the size of an atom that forms part of a single covalent bond. The sum of the covalent radii of nitrogen and fluorine gives an estimate of the bond length if we assume that the atoms are spheres that touch each other. 2. **Experimental Bond Length**: ...
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Account for the following : (i)The experimentally determined N-F bond length in NF_3 is greater than the sum of the single bond covalent radii of N and F . (ii) Mg_3 N_2 when reacted with water gives NH_3 but HCl is not obtained from MgCl_2 on reaction with water at room temperature. (iii) (SiH_3)_3 N is a weaker base than (CH_3)_3 N .

The experimentally determined N-F bond length in NF_(3) is _____than the sum of the single covalent bond radii of N and F .

The experimentally determined N-F bond length in NF_(3) is greater than the sum of the covalent raddi of N and F. Assign reason.

(a) PF_5 is known, but NF_5 is not. Why ? (b) The experimentally determined N-F bond length in NF_3 is greater than the sum of single convalent radii of N and F .

Which of the following complexes or molecules has/ have N-N bond length greater than that in free N_(2) molecule?

Give reasons for the following: NH_(3) is more polar than NF_(3) .

PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-CONCEPTUAL QUESTIONS
  1. Which d-orbital is involved in sp^(3) d hydridisation and why ?

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  2. Which d-orbital is involved in dsp^(2) hybridisation why ?

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  3. What is the hybrid state of BeCl(2) ? What will be the change in the ...

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  4. Arrange the following in order of decreasing bond angles (i)CH(4),...

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  5. Write the structure of an anion which is isostructural with BF(3) and...

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  6. Why axis bonds of PCl(5) are longer than equatorial bonds ?

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  7. Name the different type of bonds present in NH(4) Cl after drawing its...

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  8. Write two resonance structure of N2 O that satisfy the octet rule.

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  9. Which of the following species have same shape/same bond order ? N...

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  10. Taking Z-axis as the internuclear axis, explain why 2p(x) or 2p(y) ...

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  11. Compara the relative stablilties of O(2)^(-) and N(2)^(-) and comment...

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  12. (a) How bond energy veries from N(2) ^(-) to N(2)^(+) and why ? ...

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  13. N(2) has higher order than NO. Explain .

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  14. Ethanol has higher boiling point diethyl ether or ethyl amine. Why ?

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  15. Why water has maximum density at 277 K ?

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  16. How many H-bonds are formed by each H(2) O molecule and how many wat...

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  17. Though Cl has nearly same electronegativeity as N, yet there is no H-b...

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  18. Explain why HF is less viscous than H(2) O .

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  19. From each of the following pairs, select the molecule with higher valu...

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  20. Account for the following : The experimentally determined NF bond...

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