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Hydrogen bonds are formed in many compou...

Hydrogen bonds are formed in many compounds e.g. `H_(2)O`, HF, `NH_(3)`. The boiling point of such compounds depends to a extent on the strength of hydrogen bond and the number of hydrogen bonds. The correct decreasing order of the boiling points above compounds is

A

`HF gt H_(2)O gt NH_(3)`

B

`H_(2)O gt HF gt NH_(3)`

C

`NH_(3) gt HF gt H_(2)O`

D

`NH_(3)gt H_(2) O gt HF`

Text Solution

Verified by Experts

The correct Answer is:
B

Strength of H-bond is in the order : `H………..Fgt H……….Ogt H………N.`
But each `H_(2)O ` molecule is linked to 4 other `H_(2)O ` molecules through H-bonds whereas each HF molecule
is linked only to two HF molecular . Hence .b.pt .of `H_(2)O gt b.pt of HF`
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PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-NCERT EXAMPLAR PROBLEMS (MULTIPLE CHOICE QUESTIONS -I)
  1. Polarity in a molecule and hence the dipole moment depends primarily o...

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  2. The types of hybrid orbitals of nitrogen in NO(2)^(+),NO(3)^(-) and NH...

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  3. Hydrogen bonds are formed in many compounds e.g. H(2)O, HF, NH(3). The...

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  4. In PO(4)^(3-) ion, the formal charge on the oxygen atom of P-O bond...

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  5. In NO(3)^(-) ion, the number of bond pairs and lone pairs of electrons...

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  6. Which of the following species has tetrahedral geometry?

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  7. Number of pi bonds and sigma bonds in the following structer is

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  8. Which molecule/ion out of the following does not contain unpaired elec...

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  9. In which of the following molecule/ion all the bonds are not equal?

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  10. In which of the following substance will hydrogen bond be strongest...

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  11. If the electron configuration of an element is 1s^(2), 2s^(2), 2p^(6),...

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  12. Which of the following angle corresponds to sp hydridisation ?

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  13. The electronic configurations of three elements, A,B are C are give...

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  14. The electronic configuration ofhte elements. A, B and C are given belo...

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  15. The electronic configuration ofhte elements. A, B and C are given belo...

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  16. The electronic configurations of three elements, A,B are C are give...

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  17. Which of the following order of energies of molecular orbitals of N(2...

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  18. Which of the following statement is not correct from the view point of...

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  19. Which of the following options represents the correct bond order ?

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  20. The electronic configuration of the outer most shell of the most elect...

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