Home
Class 11
CHEMISTRY
{:(,"Column I(Molecular orbital)",,"Colu...

`{:(,"Column I(Molecular orbital)",,"Column II (Nodal planes present,Symmetry)"), ((A),sigma_(2s),(p),"0"),((B),sigma_(2p_(z)) ,(q),"1"),((C),pi _(2p_(x))^(**),(r),"2"),((D),pi _(2p_(y))^(**) ,(s),"Gerade"):}`
(Take Z-axis as the internuclear axis)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the molecular orbitals and their corresponding nodal planes and symmetry, we will analyze each molecular orbital listed in Column I and determine the number of nodal planes and their symmetry classification. ### Step-by-Step Solution: 1. **Identify the Molecular Orbitals:** - We have four molecular orbitals to analyze: - (A) σ₂s - (B) σ₂p(z) - (C) π₂p(x) - (D) π₂p(y) 2. **Determine the Nodal Planes and Symmetry for Each Orbital:** - **(A) σ₂s:** - **Nodal Planes:** The σ₂s molecular orbital has 0 nodal planes. - **Symmetry:** Since it has 0 nodal planes, it is classified as "Gerade" (g). - **(B) σ₂p(z):** - **Nodal Planes:** The σ₂p(z) molecular orbital has 1 nodal plane. - **Symmetry:** With 1 nodal plane, it is classified as "Ungerade" (u). - **(C) π₂p(x):** - **Nodal Planes:** The π₂p(x) molecular orbital has 1 nodal plane. - **Symmetry:** It is classified as "Ungerade" (u). - **(D) π₂p(y):** - **Nodal Planes:** The π₂p(y) molecular orbital also has 1 nodal plane. - **Symmetry:** It is classified as "Ungerade" (u). 3. **Summarize the Findings:** - (A) σ₂s: 0 nodal planes, Gerade (g) - (B) σ₂p(z): 1 nodal plane, Ungerade (u) - (C) π₂p(x): 1 nodal plane, Ungerade (u) - (D) π₂p(y): 1 nodal plane, Ungerade (u) ### Final Answers: - (A) σ₂s: (p) "0", (s) "Gerade" - (B) σ₂p(z): (q) "1", (r) "Ungerade" - (C) π₂p(x): (q) "1", (r) "Ungerade" - (D) π₂p(y): (q) "1", (r) "Ungerade"
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise COMPETITION FOCUS JEE (Main and Advanced)/ MEDICAL ENTRANCE SPECIAL (VI. INTEGER TYPE QUESTIONS)|15 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise COMPETITION FOCUS JEE (Main and Advanced)/ MEDICAL ENTRANCE SPECIAL (VII. NUMERICAL VALUE TYPE QUESTIONS (IN DECIMAL NOTATION))|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise COMPETITION FOCUS JEE (Main and Advanced)/ MEDICAL ENTRANCE SPECIAL (IV. MATCHING TYPE QUESTIONS)|6 Videos
  • APPENDIX

    PRADEEP|Exercise MODEL TEST PAPER <br> (Section C )|9 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    PRADEEP|Exercise Competition Focus (Jee Main and Advanced / Medical Entrance ) ( Assertion - Reason Type Question ) (Type II)|12 Videos

Similar Questions

Explore conceptually related problems

Select from the following molecular orbitals which are gerade ungerade (a) sigma(2s) (b) pi^(**)(2p_(x)) (c ) pi ^(**)(2p_(y)) (d) sigma^(**)(1s) (e) pi (2p_(x)) (f) pi (2p_(x)) .

{:(Column I,Column II),((A)1s,(p)m_(l)=0),((B)2p_(z),(q)"Nodal planes"=2),((C)3d_(xy),(r)"Radial nodes"=0),((D)3d_(z^(2)),(s)"Number of maxima"=1):}

Match the following : {:(,"Column-I (Orbitals)",,"Column-II (Nature and No. of Nodes)"),((A),3d_(z^(2)),(p),"One sperhical node"),((B),4d_(xy),(q), "Two nodal planes"),((C ) , 2s,(r ),"Node in yz plane"),((D) ,3p_(x),(s) , "Two angular nodes"):}

Number of nodal plane (S) present in s, p_(x),P_(y) p_(z) are respecticvely:

{:("Column-I","Column-II"),((A)NH_3, "p linear"),((B)BeF_2, "q polar"),((C )H_2O, "r" mu "=0D"),((D)CO_2, "s Angular"):}

The molecular orbital configuration of a diatomic molecule is sigma 1s^(2) sigma^(**)1s^(2)sigma2s^(2)sigma^(**)2s^(2) sigma2p_(x)^(2)pi2p_(y)^(2)pi2p_(z)^(2) Its bond order is _________.

sigma2s, pi^(**) (2p_(x)) and pi(2p_(x)) are gerade MO .