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Statement 1: o-nitrophenol has higher bo...

Statement 1: o-nitrophenol has higher boilling point than p-nitrophenol.
Statement 2: Intermolecular hydrogen bonding is present in p-nitrophenol and intrmolecular hydrogen bonding in o-nitrophenol.

A

Statement-1 is Ture , Statement-2 is Ture , Statement-2 is a correct explanation for Statement-1.

B

Statement-1 is Ture , Statement-2 is Ture , Statement-2 is not a correct explanation for Statement-1.

C

Statement-1 is True , Statement-2 is False .

D

Statement-1 is False, Statement-2 is True.

Text Solution

Verified by Experts

The correct Answer is:
d

Correct statement -1 o-Nitrophenol has lower
boiling point than p-Nirophenol.
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Explore conceptually related problems

Draw intramolecular hydrogen bonding structure in o-nitrophenol .

Assertion : Boiling point of p-nitrophenol is greater than that of o-nitrophenol. Reason : There is intramolecular hydrogen bonding in p-nitrophenol and intermolecular hydrogen bonding in o-nitrophenol.

Statement I: p-Nitrophenol is a stronger acid than o-nitrophenol. Statement II: Intramolecular hydrogen bonding makes the o-isomer weaker than p-isomer.

o-Nitrophenol has lower/higher pk_(a) value than m-nitrophenol.

A : p - nitrophenol has high pK_(a) in comparison to o-nitrophenol R : In o-nitrophenol , intermolecular H-bonding is present

PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-COMPETITION FOCUS JEE (Main and Advanced)/ MEDICAL ENTRANCE SPECIAL (VIII. ASSERTION-REASON TYPE QUESTIONS TYPE I)
  1. Assertion Both NO(3)^(Theta) and CO(3)^(2-) ions are triangular planar...

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  2. Statement 1: BF(3) moleculeis planar while NF(3) is pyramidal. State...

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  3. Statement 1: o-nitrophenol has higher boilling point than p-nitropheno...

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  4. Statement-1. The boiling point of NH(3) lies between that of SbH(3) a...

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  5. Assertion . Nitrogen shown a valency of 3 as well as 5. Reason. Lewi...

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  6. Assertion . Ionic compounds tend to be non-volatile. Reason . Ionic...

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  7. Assertion . Water is specially effective in screeniing the electrostat...

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  8. Assertion (A): SF(6) molecule is unstable. Reason (R): A stable mole...

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  9. Assertion . The bond anlge of PBr(3) is greater than that of PH(3) but...

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  10. Assertion : H-S-H bond angle in H(2)S is closer to 90^(@) but H-O-H b...

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  11. Assertion . When two hydrogen atoms approach each other to form a cova...

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  12. Assertion (A): Pi bond is never formed alone. It is formed along with ...

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  13. Assertion : The atoms in a covalent molecule are said to share el...

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  14. Assertion : Boiling points of cis-isomers are higher than trans - isom...

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  15. Assertion:- NO(3)^(-) is planar while NH(3) is pyramidal Reason:- N ...

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  16. Asseration: SeCl(4), does not havea tetrahedral structure. Reason: S...

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  17. Assertion: N(3)^(-) is a weaker base than NH(2)^(-) Reason: The lone...

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  18. Assertion(A) - BF3 molecule is planar but NF3 is pyramidal Reason( R...

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  19. Assertion . The resonance hybrid is more stable than any of the contri...

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  20. Assertion Both pi(2P(x)) and pi^(**)(2P(x))MO's have one nodal plane e...

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