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In terms of rate constants for forward a...

In terms of rate constants for forward and backward reactions `(k_(f) and k_(b))` , equilibrium constant of a reaction is equal to `…………. .`

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To find the equilibrium constant \( K \) in terms of the rate constants for the forward and backward reactions (\( k_f \) and \( k_b \)), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: Consider a general reaction at equilibrium: \[ A + B \rightleftharpoons C \] Here, \( A \) and \( B \) are reactants, and \( C \) is the product. 2. **Define Rate Constants**: - Let \( k_f \) be the rate constant for the forward reaction (where \( A \) and \( B \) form \( C \)). - Let \( k_b \) be the rate constant for the backward reaction (where \( C \) decomposes back into \( A \) and \( B \)). 3. **Write Rate Expressions**: - The rate of the forward reaction can be expressed as: \[ \text{Rate}_{\text{forward}} = k_f [A][B] \] - The rate of the backward reaction can be expressed as: \[ \text{Rate}_{\text{backward}} = k_b [C] \] 4. **Establish Equilibrium Condition**: At equilibrium, the rate of the forward reaction equals the rate of the backward reaction: \[ k_f [A][B] = k_b [C] \] 5. **Rearranging for Equilibrium Constant**: Rearranging the above equation gives: \[ \frac{[C]}{[A][B]} = \frac{k_f}{k_b} \] 6. **Define the Equilibrium Constant**: The equilibrium constant \( K \) (or \( K_c \) for concentrations) is defined as: \[ K = \frac{[C]}{[A][B]} \] 7. **Final Expression**: Therefore, we can express the equilibrium constant in terms of the rate constants: \[ K = \frac{k_f}{k_b} \] ### Final Answer: The equilibrium constant of a reaction is equal to: \[ K = \frac{k_f}{k_b} \]
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