Home
Class 11
CHEMISTRY
Ratio K(p)//K(c) of the reaction 2 SO(2)...

Ratio `K_(p)//K_(c)` of the reaction `2 SO_(2) + O_(2)hArr 2 SO_(3) ` is equal to `……… .`

Text Solution

AI Generated Solution

The correct Answer is:
To find the ratio \( \frac{K_p}{K_c} \) for the reaction: \[ 2 \text{SO}_2(g) + \text{O}_2(g) \rightleftharpoons 2 \text{SO}_3(g) \] we can use the relationship between \( K_p \) and \( K_c \): \[ K_p = K_c \cdot R T^{\Delta N_g} \] where: - \( R \) is the universal gas constant, - \( T \) is the temperature in Kelvin, - \( \Delta N_g \) is the change in the number of moles of gas, calculated as: \[ \Delta N_g = \text{moles of gaseous products} - \text{moles of gaseous reactants} \] **Step 1: Identify the moles of gaseous products and reactants.** In the given reaction: - Moles of gaseous products (SO3) = 2 - Moles of gaseous reactants (SO2 + O2) = 2 + 1 = 3 **Step 2: Calculate \( \Delta N_g \).** \[ \Delta N_g = \text{moles of products} - \text{moles of reactants} = 2 - 3 = -1 \] **Step 3: Substitute \( \Delta N_g \) into the equation for \( K_p \).** Using the relationship: \[ K_p = K_c \cdot R T^{\Delta N_g} \] we can express \( \frac{K_p}{K_c} \): \[ \frac{K_p}{K_c} = R T^{\Delta N_g} \] **Step 4: Substitute \( \Delta N_g \) into the ratio.** Since \( \Delta N_g = -1 \): \[ \frac{K_p}{K_c} = R T^{-1} = \frac{R}{T} \] Thus, the ratio \( \frac{K_p}{K_c} \) for the reaction is: \[ \frac{K_p}{K_c} = \frac{R}{T} \] ### Final Answer: \[ \frac{K_p}{K_c} = \frac{R}{T} \] ---
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise CONCEPTUAL QUESTIONS|21 Videos
  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWERS|34 Videos
  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise TEST YOUR GRIP (MULTIPLE CHOICE QUESTIONS)|15 Videos
  • EQUILIBRIUM

    PRADEEP|Exercise Competition Focus (VIII. Assertion-Reason Type Questions)|16 Videos
  • HYDROCARBONS

    PRADEEP|Exercise Competition Focus (JEE(main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS|31 Videos

Similar Questions

Explore conceptually related problems

K_(p)//K_(c) for the reaction CO(g)+1/2 O_(2)(g) hArr CO_(2)(g) is

If concentration are expressed in moles L^(-1) and pressure in atmospheres, what is the ratio of K_(p) "to" K_(c) for the reaction, 2SO_(2)(g)+O_(2)(g)harr2SO_(3)(g) at 25^(@)C ?

The equilibrium constant for the given reaction: SO_(3(g))hArrSO_(2(g))+1//2O_(2(g)) , (K_(c)=4.9xx10^(-2)) The value of K_(c) for the reaction: 2SO_(2(g))+O_(2(g))hArr2SO_(3(g)) , will be :

The equilibrium constant (K_(p)) for the reaction, 2SO_(2)+O_(2)hArr2SO_(3) at 1000 K is 3.5 . The partial pressure of oxygen gas to give equal mole of SO_(2) and SO_(3) is :

Find the value of K_(p) for the reaction : 2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g) , if the partial pressures of SO_(2), O_(2) , and SO_(3) are 0.559 atm, 0.101 atm and 0.331 atm respectively. What will be the partial pressure of O_(2) gas if at equilibrium, equal amounts (in moles) of SO_(2) and SO_(3) are observed?

For the reaction 2NO_(2(g))hArrN_(2)O_(4(g)),K_(p)//K_(c) is equal to

PRADEEP-EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES-TEST YOUR GRIP (II. FILL IN THE BLANKS)
  1. A bulb containing N(2)O(4) is colourless in ice. Its colour inboiling ...

    Text Solution

    |

  2. Equimolar amounts of H(2) and I(2) were taken in a bulb maintained at ...

    Text Solution

    |

  3. According to law of mass action rate of a chemical reaction is proport...

    Text Solution

    |

  4. In terms of rate constants for forward and backward reactions (k(f) an...

    Text Solution

    |

  5. Equilibrium constant of a reaction does not change with ……… but change...

    Text Solution

    |

  6. Ratio K(p)//K(c) of the reaction 2 SO(2) + O(2)hArr 2 SO(3) is equal ...

    Text Solution

    |

  7. Equilibrium constant for the reaction , N(2) + 3 H(2) hArr 2 NH(3) is...

    Text Solution

    |

  8. Adding a catalyst to a reaction at equilibrium

    Text Solution

    |

  9. The equilibrium constant of an endothermic reaction ……….. with increas...

    Text Solution

    |

  10. Write the expression for equilibrium constant K(p) for the reaction, ...

    Text Solution

    |

  11. If the concentration quotient of a reaction in greater than its equili...

    Text Solution

    |

  12. N(2) gas id added to the reaction equilibrium PCl(5) (g) hArr PCl(3) (...

    Text Solution

    |

  13. Solution of FeCl(3) " ( yellow )" and NH(4)SCN " (colourless) "were m...

    Text Solution

    |

  14. Exothermic reactions are favoured by in temperature

    Text Solution

    |

  15. Low pressure is favourable for those reversible reactions in which the...

    Text Solution

    |

  16. When the pressure is applied over system ice hArr wate what will happe...

    Text Solution

    |