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Equilibrium constant for the reaction , ...

Equilibrium constant for the reaction , `N_(2) + 3 H_(2) hArr 2 NH_(3) ` is K, then equilibrium constant for the reaction, `NH_(3) hArr 1/2 N_(2) + 3/2 H_(2) ` will be ` ……….. .`

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To find the equilibrium constant for the reaction \( \text{NH}_3 \rightleftharpoons \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \) given that the equilibrium constant for the reaction \( \text{N}_2 + 3 \text{H}_2 \rightleftharpoons 2 \text{NH}_3 \) is \( K \), we can follow these steps: ### Step 1: Write the original reaction and its equilibrium constant The original reaction is: \[ \text{N}_2 + 3 \text{H}_2 \rightleftharpoons 2 \text{NH}_3 \] The equilibrium constant for this reaction is given as \( K \). ### Step 2: Reverse the original reaction When we reverse the reaction, we get: \[ 2 \text{NH}_3 \rightleftharpoons \text{N}_2 + 3 \text{H}_2 \] The equilibrium constant for the reversed reaction is the reciprocal of \( K \): \[ K' = \frac{1}{K} \] ### Step 3: Adjust the coefficients Now, we need to adjust the coefficients to match the desired reaction: \[ \text{NH}_3 \rightleftharpoons \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \] To do this, we divide the entire equation by 2: \[ \text{NH}_3 \rightleftharpoons \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \] ### Step 4: Calculate the new equilibrium constant When we divide the coefficients of a balanced equation by a factor, we raise the equilibrium constant to the power of that factor. Since we divided by 2, we take the square root of the equilibrium constant from the reversed reaction: \[ K'' = (K')^{\frac{1}{2}} = \left(\frac{1}{K}\right)^{\frac{1}{2}} = \frac{1}{\sqrt{K}} \] ### Final Answer Thus, the equilibrium constant for the reaction \( \text{NH}_3 \rightleftharpoons \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \) is: \[ \frac{1}{\sqrt{K}} \]
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