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The equilibrium constant of an endotherm...

The equilibrium constant of an endothermic reaction `………..` with increase of temperature.

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To determine how the equilibrium constant (K) of an endothermic reaction changes with an increase in temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Nature of Endothermic Reactions**: - An endothermic reaction is one that absorbs heat from the surroundings. This means that the change in enthalpy (ΔH) for the reaction is positive. 2. **Recall the Relationship Between Equilibrium Constant and Temperature**: - The equilibrium constant (K) for a reaction can be expressed using the van 't Hoff equation: \[ K = A \cdot e^{-\frac{\Delta H}{RT}} \] where: - \( K \) is the equilibrium constant, - \( A \) is a pre-exponential factor, - \( \Delta H \) is the change in enthalpy, - \( R \) is the universal gas constant, - \( T \) is the temperature in Kelvin. 3. **Analyze the Effect of Temperature on K**: - Since ΔH is positive for endothermic reactions, as the temperature (T) increases, the term \(-\frac{\Delta H}{RT}\) becomes less negative (i.e., it increases). - This results in the exponential term \( e^{-\frac{\Delta H}{RT}} \) increasing, which in turn causes the equilibrium constant \( K \) to increase. 4. **Conclusion**: - Therefore, for an endothermic reaction, the equilibrium constant \( K \) increases with an increase in temperature. ### Final Answer: The equilibrium constant of an endothermic reaction **increases** with an increase in temperature.
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