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The equilibrium constant for the followi...

The equilibrium constant for the following reaction is `1.6xx10^(5)` at `1024 K`
`H_(2)(g)+Br_(2)(g) hArr 2HBr(g)`
find the equilibrium pressure of all gases if `10.0` bar of `HBr` is introduced into a sealed container at `1024 K`.

Text Solution

Verified by Experts

` {:(,2HBr (g),hArr,H_(2)(g),+,Br_(2)(g),K=1/(1*6 xx10^(5))),("Intial",10"bar",,,,,),("At eqm.",10-p,,p//2,,p//2,):}`
` K_(p) = ((p//2)( p//2))/(10-p)^(2)= 1/(1*6 xx10^(5))(p^(2))/(4(10-p)^(2) )= 1/(1*6 xx 10^(5) )`
Taking square root of both sides, we get
` p/(2(10-p) )= 1/(4 xx10^(2)) or 4 xx 10^(2) p= 2 (10-p) or 402 p = 20 or p= 20/402 = 4* 98 xx 10^(-2) "bar "`
Hence , at equilibrium `p_(H_(2)) =pBr_(2) = p//2 = 2*5 xx 10^(-2) "bar" , p_(HBr) = 10-p ~~ 10 " bar" `
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