Home
Class 11
CHEMISTRY
Each question given below contains STATE...

Each question given below contains STATEMENT -1 (Assertion) and STATEMENT -2 (Reason). It has four choice (a), (b), ( c ) and (d) out of which ONLY ONE is correct . Choose the correct option as under :
Statement -1. Equilibrium constant of an endothermic reaction increases with increase of temperature .
Statement -2. With increase in temperature , an endothermic reaction is favoured more in the forward direction.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements provided: **Statement 1 (Assertion):** The equilibrium constant of an endothermic reaction increases with an increase in temperature. **Statement 2 (Reason):** With an increase in temperature, an endothermic reaction is favored more in the forward direction. ### Step-by-Step Solution: 1. **Understanding Endothermic Reactions:** - An endothermic reaction is one that absorbs heat, which means the enthalpy change (ΔH) for the reaction is positive (ΔH > 0). 2. **Equilibrium Constant and Temperature:** - The equilibrium constant (K) for a reaction can be expressed in terms of temperature using the van 't Hoff equation: \[ \ln K = -\frac{\Delta H}{R} \cdot \frac{1}{T} + C \] - From this equation, we can see that if the temperature (T) increases, the term \(-\frac{\Delta H}{RT}\) becomes less negative (or more positive), leading to an increase in K. 3. **Conclusion on Statement 1:** - Since K increases with an increase in temperature for an endothermic reaction, **Statement 1 is true.** 4. **Effect of Temperature on Reaction Direction:** - According to Le Chatelier's principle, if we increase the temperature of an endothermic reaction, the system will shift in the direction that absorbs heat (the forward direction). - This means that more products are formed when the temperature increases. 5. **Conclusion on Statement 2:** - Since the forward reaction is favored with an increase in temperature for an endothermic reaction, **Statement 2 is also true.** 6. **Relationship Between Statements:** - Statement 2 provides a valid explanation for Statement 1. The increase in the equilibrium constant (K) due to temperature increase is because the forward reaction is favored. ### Final Answer: Both statements are true, and Statement 2 is the correct explanation for Statement 1. Therefore, the correct option is **(a)**. ---

To solve the question, we need to analyze both statements provided: **Statement 1 (Assertion):** The equilibrium constant of an endothermic reaction increases with an increase in temperature. **Statement 2 (Reason):** With an increase in temperature, an endothermic reaction is favored more in the forward direction. ### Step-by-Step Solution: ...
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise Competition Focus (Jee(Main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS (TYPE - II)|10 Videos
  • EQUILIBRIUM IN PHYSICAL AND CHEMICAL PROCESSES

    PRADEEP|Exercise Competition Focus (Jee(Main and advanced)/Medical Entrance) VII. NUMERICAL VALUE TYPE QUESTIONS|1 Videos
  • EQUILIBRIUM

    PRADEEP|Exercise Competition Focus (VIII. Assertion-Reason Type Questions)|16 Videos
  • HYDROCARBONS

    PRADEEP|Exercise Competition Focus (JEE(main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS|31 Videos